A model to simulate the gas chromatographic separation in the presence of a spatial thermal
gradient is presented. This model is developed from existing models for the prediction of …

The transfer of retention times based on thermodynamic models between columns can aid in
separation optimization and compound identification in gas chromatography. Although …

Comprehensive two-dimensional gas chromatography (GC× GC) provides enhanced
separation power over its one-dimensional counterpart–gas chromatography (GC). This …

This contribution evaluates the performance of two predictive approaches in calculating
temperature-programmed gas chromatographic retention times under vacuum outlet …

Thermodynamics‐based models have been demonstrated to be useful for predicting
retention time and peak widths in gas chromatography and two‐dimensional gas …

The Gibbs energy additivity method was used to correlate the retention time (t R) of common
fatty acid methyl esters (FAMEs) to their chemical structures. The t R of 20 standard FAMEs …

An approach that is commonly used for calculating the retention time of a compound in GC
departs from the thermodynamic properties ΔH, ΔS and ΔC p of phase change (from mobile …

Gas chromatography (GC) is a frequently applied separation technique. Nevertheless, a
suitable operational setup for reaching separation may require extensive time and …

Comprehensive two-dimensional gas chromatography (GC× GC) is a high-performance
technique for separation, identification and quantification of volatiles and semi-volatiles in …

Thermodynamics-based predictive models of retention in gas chromatography and
comprehensive two-dimensional gas chromatography have been demonstrated to provide …