Covalent organic frameworks

KT Tan, S Ghosh, Z Wang, F Wen… - Nature Reviews …, 2023 - nature.com
The dream to prepare well-defined materials drives the methodological evolution for
molecular synthesis, structural control and materials manufacturing. Among various …

Two-dimensional polymers and polymerizations

AM Evans, MJ Strauss, AR Corcos, Z Hirani… - Chemical …, 2021 - ACS Publications
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …

Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis

Y Qian, Y Han, X Zhang, G Yang, G Zhang… - Nature …, 2023 - nature.com
The strong excitonic effects widely exist in polymer-semiconductors and the large exciton
binding energy (E b) seriously limits their photocatalysis. Herein, density functional theory …

A crystalline partially fluorinated triazine covalent organic framework for efficient photosynthesis of hydrogen peroxide

H Wang, C Yang, F Chen, G Zheng… - Angewandte Chemie …, 2022 - Wiley Online Library
A partially fluorinated, metal‐free, imine‐linked two‐dimensional triazine covalent organic
framework (TF50‐COF) photocatalyst was developed. Fluorine (F)‐substituted and …

Hydrogen bonding regulated flexibility and disorder in hydrazone-linked covalent organic frameworks

Y Li, J Sui, LS Cui, HL Jiang - Journal of the American Chemical …, 2023 - ACS Publications
Covalent organic framework (COF) chemistry is experiencing unprecedented development
in recent decades. The current studies on COF chemistry are mainly focused on the …

Single-crystalline imine-linked two-dimensional covalent organic frameworks separate benzene and cyclohexane efficiently

A Natraj, W Ji, J Xin, I Castano, DW Burke… - Journal of the …, 2022 - ACS Publications
Two-dimensional (2D) covalent organic frameworks (COFs) are composed of structurally
precise, permanently porous, layered macromolecular sheets, which are traditionally …

Charge and mass transport mechanisms in two-dimensional covalent organic frameworks (2D COFs) for electrochemical energy storage devices

H Zhang, Y Geng, J Huang, Z Wang, K Du… - Energy & Environmental …, 2023 - pubs.rsc.org
The development of smartphones and electric cars calls for electrochemical energy storage
devices with higher capacities, faster charging rates, and improved safety. A key to …

2D covalent organic frameworks: from synthetic strategies to advanced optical‐electrical‐magnetic functionalities

C Wang, Z Zhang, Y Zhu, C Yang, J Wu… - Advanced …, 2022 - Wiley Online Library
Covalent organic frameworks (COFs), an emerging class of organic crystalline polymers with
highly oriented structures and permanent porosity, can adopt 2D or 3D architectures …

2D conjugated covalent organic frameworks: defined synthesis and tailor-made functions

T Zhang, G Zhang, L Chen - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Covalent organic frameworks (COFs) are an emerging class of crystalline
porous polymers and have received tremendous attention and research interest. COFs can …

Covalent organic frameworks as model materials for fundamental and mechanistic understanding of organic battery design principles

S Haldar, A Schneemann, S Kaskel - Journal of the American …, 2023 - ACS Publications
Redox-active covalent organic frameworks (COFs) have recently emerged as advanced
electrodes in polymer batteries. COFs provide ideal molecular precision for understanding …