Spin hyperpolarization in modern magnetic resonance
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …
disciplines and in various practical applications, with medical magnetic resonance imaging …
Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR
T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …
biology. While NMR can provide invaluable information about local geometry on an atomic …
[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …
diversification since its inception more than 6 decades ago. In this review we provide an in …
[HTML][HTML] Paramagnetic NMR in solution and the solid state
The field of paramagnetic NMR has expanded considerably in recent years. This review
addresses both the theoretical description of paramagnetic NMR, and the way in which it is …
addresses both the theoretical description of paramagnetic NMR, and the way in which it is …
High frequency dynamic nuclear polarization
During the three decades 1980–2010, magic angle spinning (MAS) NMR developed into the
method of choice to examine many chemical, physical, and biological problems. In …
method of choice to examine many chemical, physical, and biological problems. In …
Facing and overcoming sensitivity challenges in biomolecular NMR spectroscopy
JH Ardenkjaer‐Larsen, GS Boebinger… - Angewandte Chemie …, 2015 - Wiley Online Library
In the Spring of 2013, NMR spectroscopists convened at the Weizmann Institute in Israel to
brainstorm on approaches to improve the sensitivity of NMR experiments, particularly when …
brainstorm on approaches to improve the sensitivity of NMR experiments, particularly when …
Large molecular weight nitroxide biradicals providing efficient dynamic nuclear polarization at temperatures up to 200 K
A Zagdoun, G Casano, O Ouari… - Journal of the …, 2013 - ACS Publications
A series of seven functionalized nitroxide biradicals (the bTbK biradical and six derivatives)
are investigated as exogenous polarization sources for dynamic nuclear polarization (DNP) …
are investigated as exogenous polarization sources for dynamic nuclear polarization (DNP) …
Surface enhanced NMR spectroscopy by dynamic nuclear polarization
It is shown that surface NMR spectra can be greatly enhanced using dynamic nuclear
polarization. Polarization is transferred from the protons of the solvent to the rare nuclei …
polarization. Polarization is transferred from the protons of the solvent to the rare nuclei …
Polarization-enhanced NMR spectroscopy of biomolecules in frozen solution
DA Hall, DC Maus, GJ Gerfen, SJ Inati, LR Becerra… - Science, 1997 - science.org
Large dynamic nuclear polarization signal enhancements (up to a factor of 100) were
obtained in the solid-state magic-angle spinning nuclear magnetic resonance (NMR) …
obtained in the solid-state magic-angle spinning nuclear magnetic resonance (NMR) …
TOTAPOL: a biradical polarizing agent for dynamic nuclear polarization experiments in aqueous media
In a previous publication, we described the use of biradicals, in that case two TEMPO
molecules tethered by an ethylene glycol chain of variable length, as polarizing agents for …
molecules tethered by an ethylene glycol chain of variable length, as polarizing agents for …