Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …
structures, has drawn much attention in the recent decade from academia to industry …
Transformations of less-activated phenols and phenol derivatives via C–O cleavage
Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …
numerous advantages over commonly used aryl halides in terms of environmental …
Catalytic transformation of lignin for the production of chemicals and fuels
Biomass is any organic matter that is renewable over time. In the context of energy, this is
often used to mean plant-based materials, such as agricultural residues, forestry wastes …
often used to mean plant-based materials, such as agricultural residues, forestry wastes …
Cross-couplings using aryl ethers via C–O bond activation enabled by nickel catalysts
M Tobisu, N Chatani - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Arene synthesis has been revolutionized by the invention of catalytic cross-
coupling reactions, wherein aryl halides can be coupled with organometallic and organic …
coupling reactions, wherein aryl halides can be coupled with organometallic and organic …
Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity
J Cornella, C Zarate, R Martin - Chemical Society Reviews, 2014 - pubs.rsc.org
In 1979, the seminal work of Wenkert set the standards for the utilization of aryl and vinyl
ethers as coupling partners via C–O bond-cleavage. Although the topic remained dormant …
ethers as coupling partners via C–O bond-cleavage. Although the topic remained dormant …
Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation–hydrogenolysis process
Q Song, F Wang, J Cai, Y Wang, J Zhang… - Energy & …, 2013 - pubs.rsc.org
Valorization of native birch wood lignin into monomeric phenols over nickel-based catalysts
has been studied. High chemoselectivity to aromatic products was achieved by using Ni …
has been studied. High chemoselectivity to aromatic products was achieved by using Ni …
A mechanistic investigation of acid-catalyzed cleavage of aryl-ether linkages: implications for lignin depolymerization in acidic environments
MR Sturgeon, S Kim, K Lawrence… - ACS Sustainable …, 2014 - ACS Publications
Acid catalysis has long been used to depolymerize plant cell wall polysaccharides, and the
mechanisms by which acid affects carbohydrates have been extensively studied. Lignin …
mechanisms by which acid affects carbohydrates have been extensively studied. Lignin …
Oxidative conversion of lignin and lignin model compounds catalyzed by CeO 2-supported Pd nanoparticles
W Deng, H Zhang, X Wu, R Li, Q Zhang, Y Wang - Green chemistry, 2015 - pubs.rsc.org
The oxidative transformation of lignin into aromatic compounds is an attractive route for
chemical utilization of lignocellulosic biomass. Unlike hydrogenolysis, no consumption of …
chemical utilization of lignocellulosic biomass. Unlike hydrogenolysis, no consumption of …
Two-step, catalytic C–C bond oxidative cleavage process converts lignin models and extracts to aromatic acids
We herein report a two-step strategy for oxidative cleavage of lignin C–C bond to aromatic
acids and phenols with molecular oxygen as oxidant. In the first step, lignin β-O-4 alcohol …
acids and phenols with molecular oxygen as oxidant. In the first step, lignin β-O-4 alcohol …
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
PJ Deuss, K Barta, JG de Vries - Catalysis Science & Technology, 2014 - pubs.rsc.org
The transition from a petroleum-based infrastructure to an industry which utilises renewable
resources is one of the key research challenges of the coming years. Biomass, consisting of …
resources is one of the key research challenges of the coming years. Biomass, consisting of …