Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization

C Zhang, X Shen, Y Jin, J Cheng, C Cai… - Chemical …, 2023 - ACS Publications
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …

Transformations of less-activated phenols and phenol derivatives via C–O cleavage

Z Qiu, CJ Li - Chemical Reviews, 2020 - ACS Publications
Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …

Catalytic transformation of lignin for the production of chemicals and fuels

C Li, X Zhao, A Wang, GW Huber, T Zhang - Chemical reviews, 2015 - ACS Publications
Biomass is any organic matter that is renewable over time. In the context of energy, this is
often used to mean plant-based materials, such as agricultural residues, forestry wastes …

Cross-couplings using aryl ethers via C–O bond activation enabled by nickel catalysts

M Tobisu, N Chatani - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Arene synthesis has been revolutionized by the invention of catalytic cross-
coupling reactions, wherein aryl halides can be coupled with organometallic and organic …

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

J Cornella, C Zarate, R Martin - Chemical Society Reviews, 2014 - pubs.rsc.org
In 1979, the seminal work of Wenkert set the standards for the utilization of aryl and vinyl
ethers as coupling partners via C–O bond-cleavage. Although the topic remained dormant …

Lignin depolymerization (LDP) in alcohol over nickel-based catalysts via a fragmentation–hydrogenolysis process

Q Song, F Wang, J Cai, Y Wang, J Zhang… - Energy & …, 2013 - pubs.rsc.org
Valorization of native birch wood lignin into monomeric phenols over nickel-based catalysts
has been studied. High chemoselectivity to aromatic products was achieved by using Ni …

A mechanistic investigation of acid-catalyzed cleavage of aryl-ether linkages: implications for lignin depolymerization in acidic environments

MR Sturgeon, S Kim, K Lawrence… - ACS Sustainable …, 2014 - ACS Publications
Acid catalysis has long been used to depolymerize plant cell wall polysaccharides, and the
mechanisms by which acid affects carbohydrates have been extensively studied. Lignin …

Oxidative conversion of lignin and lignin model compounds catalyzed by CeO 2-supported Pd nanoparticles

W Deng, H Zhang, X Wu, R Li, Q Zhang, Y Wang - Green chemistry, 2015 - pubs.rsc.org
The oxidative transformation of lignin into aromatic compounds is an attractive route for
chemical utilization of lignocellulosic biomass. Unlike hydrogenolysis, no consumption of …

Two-step, catalytic C–C bond oxidative cleavage process converts lignin models and extracts to aromatic acids

M Wang, J Lu, X Zhang, L Li, H Li, N Luo, F Wang - ACS Catalysis, 2016 - ACS Publications
We herein report a two-step strategy for oxidative cleavage of lignin C–C bond to aromatic
acids and phenols with molecular oxygen as oxidant. In the first step, lignin β-O-4 alcohol …

Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals

PJ Deuss, K Barta, JG de Vries - Catalysis Science & Technology, 2014 - pubs.rsc.org
The transition from a petroleum-based infrastructure to an industry which utilises renewable
resources is one of the key research challenges of the coming years. Biomass, consisting of …