A review of functional linear carbon chains (oligoynes, polyynes, cumulenes) and their applications as molecular wires in molecular electronics and optoelectronics

MR Bryce - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Linear, sp-hybridised, 1-dimensional (1D) all-carbon wires are conceptually the simplest π-
conjugated organic molecules. Their fundamental experimental and theoretical properties …

(Hetero) arene-fused boroles: a broad spectrum of applications

J He, F Rauch, M Finze, TB Marder - Chemical Science, 2021 - pubs.rsc.org
(Hetero) arene-fused boroles are a class of compounds containing a 5-membered boron
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …

Applications of triarylborane materials in cell imaging and sensing of bio-relevant molecules such as DNA, RNA, and proteins

SM Berger, TB Marder - Materials Horizons, 2022 - pubs.rsc.org
Triarylboranes have been known for more than 100 years and have found potential
applications in various fields such as anion sensors and optoelectronics, for example in …

Donor–acceptor–acceptor-type near-infrared fluorophores that contain dithienophosphole oxide and boryl groups: effect of the boryl group on the nonradiative decay

Y Sugihara, N Inai, M Taki, T Baumgartner… - Chemical …, 2021 - pubs.rsc.org
The use of donor–π–acceptor (D–π–A) skeletons is an effective strategy for the design of
fluorophores with red-shifted emission. In particular, the use of amino and boryl moieties as …

Alkoxy-substituted quadrupolar fluorescent dyes

Y Feng, PJ Das, RM Young, PJ Brown… - Journal of the …, 2022 - ACS Publications
Polar and polarizable π-conjugated organic molecules containing push–pull chromophores
have been investigated extensively in the past. Identifying unique backbones and building …

Photodissociative Modules that Control Dual‐Emission Properties in Donor–π–Acceptor Organoborane Fluorophores

M Kawashiro, T Mori, M Ito, N Ando… - Angewandte …, 2023 - Wiley Online Library
Donor–π–acceptor fluorophores that consist of an electron‐donating amino group and an
electron‐accepting triarylborane moiety generally exhibit substantial solvatochromism in …

Solvent Polarity Governs Ultrafast Structural Dynamics: A Case Study of 4-Dimethylamino-4′-carbomethoxydiphenylacetylene

A Barak, N Dhiman, F Sturm, F Rauch… - The Journal of …, 2023 - ACS Publications
The compound 4-dimethylamino-4′-carbomethoxydiphenylacetylene (DACM-DPA) is a
donor-π-acceptor system that exhibits significant charge transfer character in the excited …

Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B− N Coordination‐Induced Dual Fluorescence

J He, F Rauch, A Friedrich, J Krebs… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Using 4‐phenylpyridine or 2‐phenylpyridine in place of biphenyl, two electron‐poor
phenylpyridyl‐fused boroles,[TipPBB1] 4 and TipPBB2 were prepared.[TipPBB1] 4 adopts a …

Fluorescent small molecules with alternating triarylamine-substituted selenophenothiophene and triarylborane: synthesis, photophysical properties and anion sensing …

G Turkoglu, T Ozturk - Dalton Transactions, 2022 - pubs.rsc.org
Two novel D–π-A fluorophores based on selenopheno [3, 2-b] thiophene, possessing
triphenylamine and 4, 4′-dimethoxytriphenylamine units as donors and dimesitylborane as …

Bis (phenylethynyl) arene Linkers in Tetracationic Bis‐triarylborane Chromophores Control Fluorimetric and Raman Sensing of Various DNAs and RNAs

M Ferger, Ž Ban, I Krošl, S Tomić… - … A European Journal, 2021 - Wiley Online Library
We report four new luminescent tetracationic bis‐triarylborane DNA and RNA sensors that
show high binding affinities, in several cases even in the nanomolar range. Three of the …