Chemical kinetics on thermal decompositions of di-tert-butyl peroxide studied by calorimetry: An overview

YS Duh, CS Kao, WLW Lee - Journal of Thermal Analysis and Calorimetry, 2017 - Springer
An overview in the field of chemical kinetics on the thermal decomposition of di-tert-butyl
peroxide (DTBP) has been performed in this study. Nowadays, DTBP has been a model …

Chemical kinetics on thermal decompositions of cumene hydroperoxide in cumene studied by calorimetry: an overview

YS Duh - Thermochimica Acta, 2016 - Elsevier
Study on chemical kinetics related to the thermal decomposition of cumene hydoperoxide
(CHP) in cumene is summarized in this work. It is of great importance to gather and compare …

Thermal hazards of benzaldehyde oxime: Based on decomposition products and kinetics analysis by adiabatic calorimeter

XQ Zhao, WQ Wu, H Li, ZC Guo, WH Chen… - Process Safety and …, 2021 - Elsevier
As a self-reactive substance, benzaldehyde oxime (BO) is prone to a highly exothermic
runaway reaction and thermal hazard analysis and the reaction kinetics calculation of BO …

Kinetic model of thermal decomposition of CL-20/HMX co-crystal for thermal safety prediction

L Zhao, Y Yin, H Sui, Q Yu, S Sun, H Zhang, S Wang… - Thermochimica …, 2019 - Elsevier
To promote the practical application of CL-20/HMX co-crystal, the understanding of its
thermal decomposition kinetics and thermal hazard prediction are highly required. In this …

Runaway reaction investigation of di‑tert‑butyl peroxide using adiabatic calorimetry

H Yan, N Yin, J Luo, B Wu, Z Tan, Q Shi - Thermochimica Acta, 2023 - Elsevier
Thermal safety assessment is an effective means to put an end to frequent chemical
accidents. The conventional safety assessment generally uses differential scanning …

An in-depth analysis of some methodical aspects of applying pseudo-adiabatic calorimetry

A Kossoy - Thermochimica Acta, 2020 - Elsevier
Abstract The Accelerating Rate Calorimeter (ARC)-the first representative of the family of
pseudo-adiabatic calorimeters-was designed for assessing reactive hazards of chemical …

Thermal decomposition behavior, thermal stability and thermal explosion risk evaluation of a novel green hydroxylamine ionic liquid salt

J Zheng, Z Li, D Zhang, Q Yang, X Zhao… - Journal of Molecular …, 2022 - Elsevier
Hydroxylamine salts are important chemical raw materials to a wide range of applications
ranging from the synthesis of caprolactam, to pesticides and medicine. However …

Model-free kinetic determination of pre-exponential factor and reaction mechanism in accelerating rate calorimetry

J Ding, X Zhang, D Hu, S Ye, J Jiang - Thermochimica Acta, 2021 - Elsevier
Accelerating rate calorimetry (ARC) is an essential tool in thermal hazard assessment of self-
reactive chemicals. Compared to the thermal analysis, the kinetic approaches for ARC are …

Heat dissipation analysis and correction of the sample in accelerating rate calorimetric experiment

D Chen, K Liu, Z Ye, G Zhang, J Xu, D Hu, J Ding - Thermochimica Acta, 2024 - Elsevier
The accelerating rate calorimeter is a commonly used tool for evaluating thermal hazards.
Due to the thermal inertia, the heat dissipation between the reaction system and the furnace …

Evaluation of the Thermal Hazard of the Oxidation Reaction in the Synthesis of 3, 4-Bis (4-nitrofurazan-3-yl) furoxan

Y Zhu, L Ding, L Xu, H Chang, X Wang… - … Process Research & …, 2022 - ACS Publications
Safety evaluation of chemical reactions is very significant before industrial applications are
conducted. A lot of thermal hazards are generated in the synthesis of 3, 4-bis (4-nitrofurazan …