To investigate how the central metalloligand geometry influences distant or vicinal metal‐to‐
metal charge‐transfer (MMCT) properties of polynuclear complexes, cis‐and trans‐isomeric …

The kinetico-mechanistic study of the formation of discrete tri-and tetranuclear mixed-
valence cyano-bridged (CoIII) 2/FeII and (CoIII) 3/FeII complexes has been carried out from …

The facile redox‐assisted assembly of a water‐soluble, extremely robust, cyanide‐bridged
mixed‐valence [{CoIII {(Me) 2 (μ‐ET) cyclen}} 2 {(μ‐NC) 2FeII (CN) 4} 2] 2− square is …

The heterotrinuclear complexes trans-and cis-[{cis-VI-L15RhIII (μ-NC)}{trans-III-L14SCoIII (μ-
NC)} FeII (CN) 4] 2+ are unprecedented examples of mixed valence complexes based on …

Novel types of water-soluble anionic cubic cages, K4 [{CoIII (Me3-Tacn)} 4 {FeII (CN) 6} 4]
and Na4 [{CoIII (Me3-Tacn)} 4 {FeII (CN) 6} 4](Me3-Tacn= 1, 4, 7-trimethyl-1, 4, 7 …

The deactivation reaction of the [CoCp (1, 4-σ-C4 [Ph] 4) PPh3] catalyst for the
cyclotrimerization of acetylenes has been kinetico-mechanistically studied under different …

The study of the [PtBr4] 2–reactivity with hexene and aniline in highly ionic (Bu4P)
Br/CH2Br2 media has been studied from a Kinetico-Mechanistic perspective. The results …

The kinetic and mechanistic study of the reaction of complexes [CoIIIXL] n+ [X= Cl, OH, H2O;
L=(NH3) 5, transL14, transL14S, in which L14 and L14S are pentadentate macrocyclic …

The preparation of an ITO (Indium Tin Oxide) modified electrode with a mixed valence Co
III/Fe II complex is described. The ITO electrode was initially modified with Au nanoparticles …

The preparation and characterization by spectroscopic and electrochemical techniques of
new dinuclear complexes of the type [(tpm)(bpy) RuII (L) RuII/III (NH3) 5] 4+/5+(bpy= 2, 2 …