Since the seminal discovery of phenyl azide by Grieß in 1864, a variety of organic azides (R–
N3) have been developed and extensively studied. The amenability of azides to a number of …

Iminoboranes are important unsaturated organoboron compounds with the formula RB≡
NR'. They are isoelectronic with alkynes, yet normally exhibit higher reactivity due to their …

Regioselective Huisgen cycloaddition reaction between 1, 2‐diboraallene and azide
proceeds under catalyst‐free and mild conditions to furnish a diboratriazole (2). X‐ray …

BN/CC isosterism is an effective strategy to build hybrid functional molecules with unique
properties. In contrast to the alkynyl iminium salts derived from cyclic (alkyl)(amino) …

While certain inorganic main‐group polymers such as silicones (polysiloxanes) are
ubiquitous in our everyday life, poly (iminoborane) s have been elusive for a long time …

Iminoboranes have gathered immense attention due to their reactivity and potential
applications as isoelectronic and isosteric alkynes. While cyclic alkynes are well …

The synthesis, characterization and reactivities of iminoborane radicals were reported. Both
X-ray analysis and density functional theory calculations revealed that the unpaired electron …