Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications
C Romain, S Bellemin-Laponnaz, S Dagorne - Coordination Chemistry …, 2020 - Elsevier
The present paper comprehensively reviews group 3–7 metal NHC complexes reported
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …
Manganese-N-heterocyclic carbene (NHC) complexes–An overview
SMPV Broeck, CSJ Cazin - Polyhedron, 2021 - Elsevier
N-heterocyclic carbenes (NHCs) have been extensively used as ligands in organometallic
complexes of the Transition Metals. This review focuses on manganese complexes bearing …
complexes of the Transition Metals. This review focuses on manganese complexes bearing …
Synthesis, stability, and (de) hydrogenation catalysis by normal and abnormal alkene-and picolyl-tethered NHC ruthenium complexes
FP Malan, E Singleton, PH Van Rooyen… - …, 2019 - ACS Publications
A series of p-cymene and cyclopentadienyl Ru (II)-aNHC complexes were synthesized from
2-methylimidazolium salts with either an N-bound alkenyl (1, 3) or picolyl tether (6, 7). The C …
2-methylimidazolium salts with either an N-bound alkenyl (1, 3) or picolyl tether (6, 7). The C …
Experimental and theoretical insights into the electronic properties of anionic N-heterocyclic dicarbenes through the rational synthesis of their transition metal …
AA Grineva, OA Filippov, Y Canac, JB Sortais… - Inorganic …, 2021 - ACS Publications
The lithiation of the NHC ligand backbone in Cp (CO) 2Mn (IMes) followed by
transmetalation on the C4 carbenic position with Cp (CO) 2FeI led to the heterobimetallic …
transmetalation on the C4 carbenic position with Cp (CO) 2FeI led to the heterobimetallic …
Toward prediction of the precatalyst activation mechanism through the cross‐coupling reactions: Reduction of Pd (II) to Pd (0) in precatalyst of the type Pd‐PEPPSI
Z Ahmadvand, M Bayat… - Journal of Computational …, 2020 - Wiley Online Library
Pd‐PEPPSI type complexes are widely used as precatalyst in a variety of organic reactions,
including the Negishi, Kumada and Suzuki‐Miyaura cross‐coupling reactions. The aim of …
including the Negishi, Kumada and Suzuki‐Miyaura cross‐coupling reactions. The aim of …
Insight into the nature of carbon–metal bonding for N-heterocyclic carbenes in gold/silver complexes and nanoparticles using DFT-correlated Raman spectroscopy …
N-Heterocyclic carbenes (NHCs) have emerged as promising ligands for stabilizing metallic
complexes, nanoclusters, nanoparticles (NPs) and surfaces. The carbon–metal bond …
complexes, nanoclusters, nanoparticles (NPs) and surfaces. The carbon–metal bond …
Influence of triphosphine ligand coordination geometry in Mn (i) hydride complexes [(P∩ P∩ P)(CO) 2 MnH] on their kinetic hydricity
SA Kovalenko, ES Gulyaeva, ES Osipova… - Dalton …, 2025 - pubs.rsc.org
Octahedral Mn (I) complexes bearing tridentate donor ligands [(L∩ L′∩ L′′)(CO) 2MnX]
have recently emerged as major players in catalytic (de) hydrogenation processes. While …
have recently emerged as major players in catalytic (de) hydrogenation processes. While …
Computational (DFT) and Experimental (NMR) Study of the Chelation of an Iridium Hyperpolarization Transfer Catalyst by Amino Acids
MJ Bouma, RLEG Aspers, M Tessari… - European Journal of …, 2023 - Wiley Online Library
Abstract Non‐hydrogenative Para‐Hydrogen Induced Hyperpolarization (nhPHIP) is a
Nuclear Magnetic Resonance (NMR) hyperpolarization technique which has experimentally …
Nuclear Magnetic Resonance (NMR) hyperpolarization technique which has experimentally …
Half‐Sandwich Manganese Complex Bearing Fused Oxazoline‐NHC Ligand: Conformational Analysis and Evaluation in Asymmetric Ketone Hydrosilylation
M Cavailles, OA Filippov, V César… - European Journal of …, 2023 - Wiley Online Library
The first manganese complex bearing a chiral N‐heterocyclic carbene (NHC) ligand was
prepared and studied by spectroscopic methods and X‐ray diffraction. While IR …
prepared and studied by spectroscopic methods and X‐ray diffraction. While IR …
CO‐Preserving Photoinduced Transfer of Cymantrenyl Moiety: a Tandem Experimental and Computational Investigation
VA Chaliy, ES Kelbysheva… - … A European Journal, 2023 - Wiley Online Library
Cyclopentadienyl manganese tricarbonyl (cymantrene) is known to undergo photochemical
reactions by releasing one of its CO ligands. Here we present the first example of a …
reactions by releasing one of its CO ligands. Here we present the first example of a …