The formation and degradation of active species during methanol conversion over protonated zeotype catalysts
U Olsbye, S Svelle, KP Lillerud, ZH Wei… - Chemical Society …, 2015 - pubs.rsc.org
The methanol to hydrocarbon (MTH) process provides an efficient route for the conversion of
carbon-based feedstocks into olefins, aromatics and gasoline. Still, there is room for …
carbon-based feedstocks into olefins, aromatics and gasoline. Still, there is room for …
Methanol-to-hydrocarbons: catalytic materials and their behavior
M Stöcker - Microporous and mesoporous materials, 1999 - Elsevier
The literature related to methanol-to-hydrocarbons (MTHC) technology over the past two
decades has been reviewed, covering mainly the methanol-to-olefin (MTO) and methanol-to …
decades has been reviewed, covering mainly the methanol-to-olefin (MTO) and methanol-to …
Mechanism of the catalytic conversion of methanol to hydrocarbons
S Ilias, A Bhan - Acs Catalysis, 2013 - ACS Publications
The discovery of the dual aromatic-and olefin-based catalytic cycles in methanol-to-
hydrocarbons (MTH) catalysis on acid zeolites has given a new context for rationalizing …
hydrocarbons (MTH) catalysis on acid zeolites has given a new context for rationalizing …
Coke formation and deactivation pathways on H-ZSM-5 in the conversion of methanol to olefins
S Müller, Y Liu, M Vishnuvarthan, X Sun… - Journal of …, 2015 - Elsevier
The role of parallel and sequential reactions in Brønsted acid-catalyzed conversion of
methanol to olefins (MTO) on H-ZSM-5 was explored by comparing the catalysis in plug-flow …
methanol to olefins (MTO) on H-ZSM-5 was explored by comparing the catalysis in plug-flow …
Acid-promoter-free ethylene methoxycarbonylation over Ru-clusters/ceria: the catalysis of interfacial Lewis acid–base pair
J An, Y Wang, J Lu, J Zhang, Z Zhang… - Journal of the …, 2018 - ACS Publications
The interface of metal-oxide plays pivotal roles in catalytic reactions, but its catalytic function
is still not clear. In this study, we report the high activity of nanostructured Ru/ceria (Ru …
is still not clear. In this study, we report the high activity of nanostructured Ru/ceria (Ru …
Specificity of sites within eight-membered ring zeolite channels for carbonylation of methyls to acetyls
The acid-catalyzed formation of carbon− carbon bonds from C1 precursors via CO insertion
into chemisorbed methyl groups occurs selectively within eight-membered ring (8-MR) …
into chemisorbed methyl groups occurs selectively within eight-membered ring (8-MR) …
Molecular dimensions for adsorptives
CE Webster, RS Drago, MC Zerner - Journal of the American …, 1998 - ACS Publications
Pore volumes, accessible surface areas, and the thermodynamics of adsorption are
essential in the understanding of solid surface characteristics fundamental to catalyst and …
essential in the understanding of solid surface characteristics fundamental to catalyst and …
Methane to acetic acid over Cu-exchanged zeolites: mechanistic insights from a site-specific carbonylation reaction
K Narsimhan, VK Michaelis, G Mathies… - Journal of the …, 2015 - ACS Publications
The selective low temperature oxidation of methane is an attractive yet challenging pathway
to convert abundant natural gas into value added chemicals. Copper-exchanged ZSM-5 and …
to convert abundant natural gas into value added chemicals. Copper-exchanged ZSM-5 and …
A link between reactivity and local structure in acid catalysis on zeolites
The extent to which spatial constraints influence rates and pathways in catalysis depends on
the structure of intermediates, transition states, and active sites involved. We aim to answer …
the structure of intermediates, transition states, and active sites involved. We aim to answer …
Solid-state NMR studies of molecular sieve catalysts
J Klinowski - Chemical reviews, 1991 - ACS Publications
Molecular sieves are a class of porous open-framework solids, which includes
aluminosilicates (zeolites), aluminophosphates, and silicoaluminophosphates of div-erse …
aluminosilicates (zeolites), aluminophosphates, and silicoaluminophosphates of div-erse …