Cleavage of Si–H, B–H, and C–H bonds by metal–ligand cooperation: focus review

T Higashi, S Kusumoto, K Nozaki - Chemical reviews, 2019 - ACS Publications
Metal–ligand cooperation, in which metal and ligand participate in bond cleavage and
formation, is gathering great attention in recent years. In contrast to the classical bond …

1, 3-N, O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles

MW Drover, JA Love, LL Schafer - Chemical Society Reviews, 2017 - pubs.rsc.org
1, 3-N, O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral
amino acids in metalloproteins. These structural units also display diverse coordination …

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands

JC Axtell, KO Kirlikovali, PI Djurovich… - Journal of the …, 2016 - ACS Publications
We report the development of a new class of phosphorescent zwitterionic bis (heteroleptic) Ir
(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl …

Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts

GM Adams, AL Colebatch, JT Skornia… - Journal of the …, 2018 - ACS Publications
A systematic study of the catalyst structure and overall charge for the dehydropolymerization
of H3B· NMeH2 to form N-methyl polyaminoborane is reported using catalysts based upon …

Cooperative B–H and Si–H Bond Activations by κ2-N,S-Chelated Ruthenium Borate Complexes

M Zafar, R Ramalakshmi, A Ahmad… - Inorganic …, 2021 - ACS Publications
Cooperative E–H (E= B, Si) bond activations employing κ2-N, S-chelated ruthenium borate
species,[PPh3 {κ2-N, S-(NS2C7H4)} Ru {κ3-H, S, S′-H2B (NC7H4S2) 2}],(1) are …

Dehydrogenation of dimethylamine–borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* noninnocence

S Pal, S Kusumoto, K Nozaki - Organometallics, 2018 - ACS Publications
Half-sandwich Cp* RhIII complexes (Cp*= η5-1, 2, 3, 4, 5-pentamethylcyclopentadienyl)
supported by 2, 2′-bipyridine or 4, 4′-di-tert-butyl-2, 2′-bipyridine catalyze …

Chiral B–N AIEgens: Intense Blue Circularly Polarized Luminescence and Piezochromism

NK Kalluvettukuzhy, P Sudhakar, J Eyyathiyil… - Organic …, 2023 - ACS Publications
We present a new class of blue circularly polarized luminescent emitters based on
tetraarylaminoborane (TAAB) with considerable dissymmetry factor in the solid state. The …

Evidence for a Bis (Elongated σ)-dihydrideborate coordinated to osmium

JC Babón, MA Esteruelas, I Fernández… - Inorganic …, 2018 - ACS Publications
The formation and Atoms in Molecules (AIM) analysis of osmium (IV) and osmium (II)
complexes containing dihydrideborate groups and primary aminoborane ligands are …

Design, Synthesis, and Chemistry of Bis (σ) borate and Agostic Complexes of Group 7 Metals

K Saha, R Ramalakshmi, S Gomosta… - … A European Journal, 2017 - Wiley Online Library
A series of new bis (σ) borate and agostic complexes of group 7 metals have been
synthesized and structurally characterized from various borate ligands, such as trihydrobis …

Linear and macrocyclic oligo (p-phenylene iminoboranes) with ferrocenyl side groups–observation of selective, non-templated macrocyclization

JS Schneider, I Krummenacher… - Chemical …, 2023 - pubs.rsc.org
A series of linear oligo (p-phenylene iminoboranes), which are BN-modified congeners of
oligo (p-phenylene vinylenes), featuring pendent ferrocene groups have been prepared …