New analytical tools for advanced mechanistic studies in catalysis: photoionization and photoelectron photoion coincidence spectroscopy
P Hemberger, JA van Bokhoven… - Catalysis Science & …, 2020 - pubs.rsc.org
What are the reaction mechanisms responsible for the selective product formation in
catalysis? How can we identify the reactive intermediates steering the reaction towards the …
catalysis? How can we identify the reactive intermediates steering the reaction towards the …
Surface Species in Photocatalytic Methanol Reforming on Pt/TiO2(110): Learning from Surface Science Experiments for Catalytically Relevant Conditions
CA Walenta, C Courtois, SL Kollmannsberger… - ACS …, 2020 - ACS Publications
Photocatalytic hydrogen evolution from methanol is a standard test reaction for photocatalyst
materials. Surprisingly, the exact chemical mechanism is still widely discussed in the …
materials. Surprisingly, the exact chemical mechanism is still widely discussed in the …
Thermal control of selectivity in photocatalytic, water-free alcohol photoreforming
SL Kollmannsberger, CA Walenta, C Courtois… - ACS …, 2018 - ACS Publications
The selective oxidation of alcohols has attracted a great deal of attention. While most
photocatalytic studies focus on the generation of hydrogen from alcohols, there is also a …
photocatalytic studies focus on the generation of hydrogen from alcohols, there is also a …
[HTML][HTML] Chirality detection of surface desorption products using photoelectron circular dichroism
G Westphal, J Wega, REA Dissanayake… - The Journal of Chemical …, 2020 - pubs.aip.org
Chirality detection of gas-phase molecules at low concentrations is challenging as the
molecular number density is usually too low to perform conventional circular dichroism …
molecular number density is usually too low to perform conventional circular dichroism …
Unravelling reaction products of styrene oxide adsorbed on ag (111) using rempi-assisted temperature-programmed desorption
G Westphal, M Wallrabe… - The Journal of Physical …, 2019 - ACS Publications
Adsorption of styrene oxide on Ag (111) at 200 K leads to the formation of a stable
oxametallacycle by ring-opening of the epoxide. At elevated temperatures, the …
oxametallacycle by ring-opening of the epoxide. At elevated temperatures, the …