Photoluminescent and Photoresponsive Iptycene‐Incorporated π‐Conjugated Systems: Fundamentals and Applications

CW Chiu, JS Yang - ChemPhotoChem, 2020 - Wiley Online Library
Iptycene is a class of 3D, rigid, and arene‐rich frameworks and has been incorporated into
photoactive π‐systems for a variety of purposes, including tuning interchromophore …

Synthesis and Characterization of a Pentiptycene‐Derived Dual Oligoparaphenylene Nanohoop

W Xu, XD Yang, XB Fan, X Wang… - Angewandte Chemie …, 2019 - Wiley Online Library
Structural designs combining oligoparaphenylene‐derived nanohoops with other functional
organic building blocks should lead to novel molecular architectures with intriguing …

Highly sensitive and discriminative detection of BTEX in the vapor phase: a film-based fluorescent approach

Z Wang, K Liu, X Chang, Y Qi, C Shang… - … applied materials & …, 2018 - ACS Publications
BTEX (benzene, toluene, ethylbenzene, o-xylene, m-xylene, and p-xylene) represents a
group of volatile organic compounds (VOCs) and constitutes a great threat to human health …

A robust platform to construct molecular patchy particles with a pentiptycene skeleton toward controlled mesoscale structures

W Xu, Y Wang, QY Guo, X Wang, Y Liu, FG Bian… - Polymer …, 2022 - pubs.rsc.org
Patchy particles with novel architectures and diverse applications have attracted significant
attention in recent years. Nevertheless, the synthesis of well-defined nanosized patchy …

Zn‐Based Metal–Organic Frameworks Using Triptycene Hexacarboxylate Ligands: Synthesis, Structure, and Gas‐Sorption Properties

K Sugamata, S Yamada, D Yanagisawa… - … A European Journal, 2023 - Wiley Online Library
A series of metal–organic frameworks (MOFs) based on zinc ions and two triptycene ligands
of different size have been synthesized under solvothermal conditions. Structural analyses …

[HTML][HTML] Improved Access to Chiral Tetranaphthoazepinium-Based Organocatalysts Using Aqueous Ammonia as Nitrogen Source

A Manaprasertsak, S Tharamak, C Schedl, A Roller… - Molecules, 2019 - mdpi.com
The class of 3, 3′-diaryl substituted tetranaphthobisazepinium bromides has found wide
application as highly efficient C 2-symmetrical phase-transfer catalysts (PTCs, Maruoka type …

Aromatic Substitution

MR Crampton - … Reaction Mechanisms· 2017: An annual survey …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Introduction General Nucleophilic
Substitution The S NAr Mechanism Meisenheimer and Related Complexes Benzyne and …

When Substituents Do Not Matter: Frontier Orbitals Explain the Unusually High and Invariant Oxidation Potential in Alkoxy-, Alkyl-, and H-Substituted Iptycenes

MV Ivanov, D Wang, SH Wadumethridge… - The Journal of …, 2017 - ACS Publications
Frontier molecular orbitals (FMOs) have played a critical role in predicting
reactivity/selectivity of pericyclic reactions. Here we show that the structurally similar …

Construction of new fluorophores by Diels-Alder reaction of diacenaphthothiophenes

Y Yamamoto, Y Fukuoka, J Nishida, C Kitamura… - Tetrahedron, 2017 - Elsevier
Abstract The Diels–Alder (DA) reaction of diacenaphtheno [1, 2-b; 1′, 2′-d] thiophene (1a)
with benzyne affords 1: 1 and 1: 2 adducts, 7 and 8, in 47 and 11% yields. An X-ray …

[引用][C] Photoluminescent and Photoresponsive Iptycene‐Incorporated π‐Conjugated Systems: Fundamentals and Applications

JS Yang, CW Chiu - ChemPhotoChem - Wiley Online Library