Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Maximizing the synergistic effect of CoNi catalyst on α-MoC for robust hydrogen production

Y Ge, X Qin, A Li, Y Deng, L Lin, M Zhang… - Journal of the …, 2020 - ACS Publications
We report the syntheses of highly dispersed CoNi bimetallic catalysts on the surface of α-
MoC based on the strong metal support interaction (SMSI) effect. The interaction between …

Cyclic (alkyl)-and (aryl)-(amino) carbene coinage metal complexes and their applications

R Jazzar, M Soleilhavoup, G Bertrand - Chemical reviews, 2020 - ACS Publications
Cyclic (alkyl)-and (aryl)-(amino) carbenes (CAACs and CAArCs) are stronger σ-donors and
π-acceptors than imidazol-2-ylidenes and imidazolidin-2-ylidenes, the well-known N …

Highly Selective and Sharp Volcano-type Synergistic Ni2Pt@ZIF-8-Catalyzed Hydrogen Evolution from Ammonia Borane Hydrolysis

F Fu, C Wang, Q Wang… - Journal of the …, 2018 - ACS Publications
Ammonia borane hydrolysis is considered as a potential means of safe and fast method of
H2 production if it is efficiently catalyzed. Here a series of nearly monodispersed alloyed …

Anion-exchange membranes in electrochemical energy systems

JR Varcoe, P Atanassov, DR Dekel… - Energy & …, 2014 - pubs.rsc.org
This article provides an up-to-date perspective on the use of anion-exchange membranes in
fuel cells, electrolysers, redox flow batteries, reverse electrodialysis cells, and …

Boron: its role in energy‐related processes and applications

Z Huang, S Wang, RD Dewhurst… - Angewandte Chemie …, 2020 - Wiley Online Library
Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …

[HTML][HTML] Recent developments in state-of-the-art hydrogen energy technologies–review of hydrogen storage materials

R Nagar, S Srivastava, SL Hudson, SL Amaya… - Solar Compass, 2023 - Elsevier
Hydrogen energy has been assessed as a clean and renewable energy source for future
energy demand. For harnessing hydrogen energy to its fullest potential, storage is a key …

The hydrogen‐storage challenge: nanoparticles for metal‐catalyzed ammonia borane dehydrogenation

CD Mboyi, D Poinsot, J Roger, K Fajerwerg, ML Kahn… - Small, 2021 - Wiley Online Library
Dihydrogen is one of the sustainable energy vectors envisioned for the future. However, the
rapidly reversible and secure storage of large quantities of hydrogen is still a technological …

Ammonia–borane and amine–borane dehydrogenation mediated by complex metal hydrides

A Rossin, M Peruzzini - Chemical reviews, 2016 - ACS Publications
This review is a comprehensive survey of the last 10 years of research on ammonia–borane
and amine–borane dehydrogenation mediated by complex metal hydrides (CMHs), within …