Group 1 and 2 and early transition metal complexes bearing N-heterocyclic carbene ligands: coordination chemistry, reactivity, and applications

S Bellemin-Laponnaz, S Dagorne - Chemical Reviews, 2014 - ACS Publications
N-Heterocyclic carbenes (NHCs) are omnipresent ligands in coordination and
organometallic chemistry, which is reflected by myriads of applications involving NHC …

Complexes bearing protic N-heterocyclic carbene ligands

S Kuwata, FE Hahn - Chemical reviews, 2018 - ACS Publications
Complexes bearing protic N-heterocyclic carbenes (protic NHCs, pNHCs), defined as cyclic
carbenes stabilized by two heteroatoms including at least one NH group, have been less …

Group 7 transition metal complexes with N-heterocyclic carbenes

SJ Hock, LA Schaper, WA Herrmann… - Chemical Society …, 2013 - pubs.rsc.org
This tutorial review summarizes all works and highlights recent advances published in the
growing field of group 7 N-heterocyclic carbene (NHC) complexes. It provides a valuable …

Re(I) NHC Complexes for Electrocatalytic Conversion of CO2

CJ Stanton III, CW Machan, JE Vandezande… - Inorganic …, 2016 - ACS Publications
The modular construction of ligands around an N-heterocyclic carbene building block
represents a flexible synthetic strategy for tuning the electronic properties of metal …

β‐Protic Pyrazole and N‐Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal–Ligand Cooperative Bifunctional Catalysis

S Kuwata, T Ikariya - Chemistry–A European Journal, 2011 - Wiley Online Library
This Minireview provides an overview of the chemistry of pyrazole and N‐heterocyclic
carbene (NHC) complexes bearing an NH group at the β‐position to the metal. The …

Early/Late Heterobimetallic Tantalum/Rhodium Species Assembled Through a Novel Bifunctional NHC‐OH Ligand

R Srivastava, R Moneuse, J Petit… - … A European Journal, 2018 - Wiley Online Library
The straightforward synthesis of a new unsymmetrical hydroxy‐tethered N‐heterocyclic
carbene (NHC) ligand, HL, is presented. The free ligand exhibits an unusual OH–carbene …

Benzannulated Re (i)–NHC complexes: Synthesis, photophysical properties and antimicrobial activity

D Siegmund, N Lorenz, Y Gothe, C Spies… - Dalton …, 2017 - pubs.rsc.org
A series of novel Re (I)(CO) 3–NHC complexes bearing unsubstituted benzimidazol-2-
ylidene ligands as well as a variety of bisimine ligands has been prepared and …

Benzimidazolyl palladium complexes as highly active and general bifunctional catalysts in sustainable cross-coupling reactions

J Zhu, VNG Lindsay - ACS Catalysis, 2019 - ACS Publications
A family of air-and moisture-stable dinuclear palladium complexes bearing 2-benzimidazolyl
ligands is reported and shown to be a highly effective and general catalytic platform in …

Carbon–Silicon and Carbon–Carbon Bond Formation by Elimination Reactions at Metal N-Heterocyclic Carbene Complexes

PL Arnold, ZR Turner, R Bellabarba… - Journal of the American …, 2011 - ACS Publications
Two functional groups can be delivered at once to organo-rare earth complexes,(L) MR2
and (L) 2MR (M= Sc, Y; L=({1-C (NDippCH2CH2N)} CH2CMe2O), Dipp= 2, 6-i Pr2-C6H3; …

N-Heterocyclic carbenes as π*-acceptors in luminescent Re (I) triscarbonyl complexes

LA Casson, S Muzzioli, P Raiteri, BW Skelton… - Dalton …, 2011 - pubs.rsc.org
Two rhenium (I) carbonyl complexes of the type fac-[Re (CO) 3 (N⁁ C) X] where N⁁ C is an
N-heterocyclic carbene [3-butyl-1-(2′-pyridyl) benzimidazolin-2-ylidene] and X is either Cl …