Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR
T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …
biology. While NMR can provide invaluable information about local geometry on an atomic …
[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …
diversification since its inception more than 6 decades ago. In this review we provide an in …
Highly efficient, water‐soluble polarizing agents for dynamic nuclear polarization at high frequency
C Sauvée, M Rosay, G Casano… - Angewandte Chemie …, 2013 - Wiley Online Library
Dynamic nuclear polarization coupled to solid-state NMR spectroscopy (DNP/ssNMR) is
emerging as a very powerful technique to overcome the limitations resulting from the …
emerging as a very powerful technique to overcome the limitations resulting from the …
High frequency dynamic nuclear polarization
During the three decades 1980–2010, magic angle spinning (MAS) NMR developed into the
method of choice to examine many chemical, physical, and biological problems. In …
method of choice to examine many chemical, physical, and biological problems. In …
Solid-state NMR studies of amyloid fibril structure
R Tycko - Annual review of physical chemistry, 2011 - annualreviews.org
Current interest in amyloid fibrils stems from their involvement in neurodegenerative and
other diseases and from their role as an alternative structural state for many peptides and …
other diseases and from their role as an alternative structural state for many peptides and …
Surface enhanced NMR spectroscopy by dynamic nuclear polarization
It is shown that surface NMR spectra can be greatly enhanced using dynamic nuclear
polarization. Polarization is transferred from the protons of the solvent to the rare nuclei …
polarization. Polarization is transferred from the protons of the solvent to the rare nuclei …
Recent developments in MAS DNP-NMR of materials
AGM Rankin, J Trébosc, F Pourpoint… - Solid State Nuclear …, 2019 - Elsevier
Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …
level structure and dynamics of materials. Nevertheless, the use of this technique is often …
Efficient dynamic nuclear polarization at 800 MHz/527 GHz with trityl‐nitroxide biradicals
Cross‐effect (CE) dynamic nuclear polarization (DNP) is a rapidly developing technique that
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …
Solid-state dynamic nuclear polarization at 263 GHz: spectrometer design and experimental results
M Rosay, L Tometich, S Pawsey, R Bader… - Physical Chemistry …, 2010 - pubs.rsc.org
Dynamic Nuclear Polarization (DNP) experiments transfer polarization from electron spins to
nuclear spins with microwave irradiation of the electron spins for enhanced sensitivity in …
nuclear spins with microwave irradiation of the electron spins for enhanced sensitivity in …
Theory for cross effect dynamic nuclear polarization under magic-angle spinning in solid state nuclear magnetic resonance: The importance of level crossings
KR Thurber, R Tycko - The Journal of chemical physics, 2012 - pubs.aip.org
We present theoretical calculations of dynamic nuclear polarization (DNP) due to the cross
effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin …
effect in nuclear magnetic resonance under magic-angle spinning (MAS). Using a three-spin …