Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Porous metal-organic frameworks for gas storage and separation: Status and challenges

H Li, L Li, RB Lin, W Zhou, Z Zhang, S Xiang, B Chen - EnergyChem, 2019 - Elsevier
Gases are widely used as energy resources for industry and our daily life. Developing
energy cost efficient porous materials for gas storage and separation is of fundamentally and …

Machine learning the quantum-chemical properties of metal–organic frameworks for accelerated materials discovery

AS Rosen, SM Iyer, D Ray, Z Yao, A Aspuru-Guzik… - Matter, 2021 - cell.com
The modular nature of metal–organic frameworks (MOFs) enables synthetic control over
their physical and chemical properties, but it can be difficult to know which MOFs would be …

Recent advances in gas storage and separation using metal–organic frameworks

H Li, K Wang, Y Sun, CT Lollar, J Li, HC Zhou - Materials Today, 2018 - Elsevier
Gas storage and separation are closely associated with the alleviation of greenhouse effect,
the widespread use of clean energy, the control of toxic gases, and various other aspects in …

Metal–organic framework materials for the separation and purification of light hydrocarbons

WG Cui, TL Hu, XH Bu - Advanced Materials, 2020 - Wiley Online Library
The separation and purification of light hydrocarbons (LHs) mixtures is one of the most
significantly important but energy demanding processes in the petrochemical industry. As an …

Tunable acetylene sorption by flexible catenated metal–organic frameworks

M Bonneau, C Lavenn, JJ Zheng, A Legrand… - Nature Chemistry, 2022 - nature.com
The safe storage of flammable gases, such as acetylene, is essential for current industrial
purposes. However, the narrow pressure (P) and temperature range required for the …

Supramolecular control of MOF pore properties for the tailored guest adsorption/separation applications

D Wu, PF Zhang, GP Yang, L Hou, WY Zhang… - Coordination Chemistry …, 2021 - Elsevier
Because the adsorption/separation process plays a great role in chemical, petrochemical,
pharmaceutical, environmental protection and many other fields, it has received extensive …

Chemistry of soft porous crystals: structural dynamics and gas adsorption properties

S Krause, N Hosono, S Kitagawa - … Chemie International Edition, 2020 - Wiley Online Library
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …

Exploration of porous metal–organic frameworks for gas separation and purification

RB Lin, S Xiang, H Xing, W Zhou, B Chen - Coordination chemistry reviews, 2019 - Elsevier
As a new generation of porous materials, metal–organic frameworks (MOFs, also known as
porous coordination polymers) have shown great promise for gas separation and …

Optimized separation of acetylene from carbon dioxide and ethylene in a microporous material

RB Lin, L Li, H Wu, H Arman, B Li, RG Lin… - Journal of the …, 2017 - ACS Publications
Selective separation of acetylene (C2H2) from carbon dioxide (CO2) or ethylene (C2H4)
needs specific porous materials whose pores can realize sieving effects while pore surfaces …