3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Achieving site-selectivity for C–H activation processes based on distance and geometry: a carpenter's approach

G Meng, NYS Lam, EL Lucas… - Journal of the …, 2020 - ACS Publications
The ability to differentiate between highly similar C–H bonds in a given molecule remains a
fundamental challenge in organic chemistry. In particular, the lack of sufficient steric and …

[图书][B] Stereochemistry of organic compounds

EL Eliel, SH Wilen - 1994 - books.google.com
Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on
this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to …

Developing ligands for palladium (II)-catalyzed C–H functionalization: intimate dialogue between ligand and substrate

KM Engle, JQ Yu - The Journal of organic chemistry, 2013 - ACS Publications
Homogeneous transition-metal-catalyzed reactions are indispensable to all facets of modern
chemical synthesis. It is thus difficult to imagine that for much of the early 20th century, the …

A review of fatty epoxide ring opening reactions: Chemistry, recent advances, and applications

BR Moser, SC Cermak, KM Doll… - Journal of the …, 2022 - Wiley Online Library
Fatty epoxides are produced from the corresponding alkenes by oxidation in the presence of
peracids or other oxidants. The classic method is the Prilezhaev epoxidation in which …

Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes

W Zhang, JL Loebach, SR Wilson… - Journal of the American …, 1990 - ACS Publications
Figure 1. Structure of catalysts 1 and 2. ortep view of the cation of (S, S)-l-[acetone] 2. but the
substratesmust bear specific functional groups to achieve the precoordination required for …

Asymmetric catalysis by architectural and functional molecular engineering: practical chemo‐and stereoselective hydrogenation of ketones

R Noyori, T Ohkuma - Angewandte Chemie International …, 2001 - Wiley Online Library
Hydrogenation is a core technology in chemical synthesis. High rates and selectivities are
attainable only by the coordination of structurally well‐designed catalysts and suitable …

Isolation and synthesis of biologically active carbazole alkaloids

HJ Knölker, KR Reddy - Chemical reviews, 2002 - ACS Publications
Carbazole 1 was isolated first from coal tar in 1872 by Graebe and Glazer (Figure 1). 1 In
1965, Chakraborty et al. described the isolation and antibiotic properties of murrayanine …

Industrial methods for the production of optically active intermediates

M Breuer, K Ditrich, T Habicher, B Hauer… - Angewandte Chemie …, 2004 - Wiley Online Library
Enantiomerically pure amino acids, amino alcohols, amines, alcohols, and epoxides play an
increasingly important role as intermediates in the pharmaceutical industry and …

Homogeneous and heterogeneous catalysis: bridging the gap through surface organometallic chemistry

C Copéret, M Chabanas… - Angewandte Chemie …, 2003 - Wiley Online Library
Surface organometallic chemistry is an area of heterogeneous catalysis which has recently
emerged as a result of a comparative analysis of homogeneous and heterogeneous …