From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Magnetism in carbon-based fiber materials

V Ranade, S Gautam, KH Chae - Journal of Magnetism and Magnetic …, 2023 - Elsevier
Metal-free ferromagnetic materials have gained significant attention as an appealing
alternative to traditional inorganic magnets due to their biocompatibility, biodegradability …

Significant charge transport effects due to subtle molecular changes in nitroxide radical single crystals

Z Liang, SN Hsu, Y Tan, H Tahir, HJ Kim, K Liu… - Cell Reports Physical …, 2023 - cell.com
Radical-containing materials have received renewed interest due to their charge-conducting
properties. However, most work focuses on macromolecules, while less attention has been …

Metal-free organic radical spin source

C Nicolaides, F Bazzi, E Vouros, DF Flesariu… - Nano Letters, 2023 - ACS Publications
Organic radicals have long been suggested as candidates for organic magnets and
components in organic spintronic devices. Herein, we demonstrate spin current emission …

Anion-induced robust ferroelectricity in sulfurized pseudo-rhombohedral epitaxial BiFeO 3 thin films via polarization rotation

G Xi, Z Pan, YW Fang, J Tu, H Li, Q Yang, C Liu… - Materials …, 2023 - pubs.rsc.org
Polarization rotation caused by various strains, such as substrate and/or chemical strain, is
essential to control the electronic structure and properties of ferroelectric materials. This …

Thermally Ultrarobust S = 1/2 Tetrazolinyl Radicals: Synthesis, Electronic Structure, Magnetism, and Nanoneedle Assemblies on Silicon Surface

Z Yang, M Pink, EM Nowik-Boltyk, S Lu… - Journal of the …, 2023 - ACS Publications
Open-shell organic molecules, including S= 1/2 radicals, may provide enhanced properties
for several emerging technologies; however, relatively few synthesized to date possess …

[HTML][HTML] Design of magnetic organic molecules and organic magnets: experiment, theory and computation with application and recent advances

SN Datta, AK Pal, A Panda - Chemical Physics Impact, 2023 - Elsevier
We begin by reviewing the early developments in the synthesis of high-spin organic
molecules and the simultaneous rationalization of the ground states of high spin. A number …

Long-Term Degradation Mechanisms in Application-Implemented Radical Thin Films

EM Nowik-Boltyk, T Junghoefer, M Glaser… - … Applied Materials & …, 2023 - ACS Publications
Blatter radical derivatives are very attractive due to their potential applications, ranging from
batteries to quantum technologies. In this work, we focus on the latest insights regarding the …

Radical‐Induced Changes in Transition Metal Interfacial Magnetic Properties: A Blatter Derivative on Polycrystalline Cobalt

EM Nowik‐Boltyk, T Junghoefer… - Angewandte Chemie …, 2024 - Wiley Online Library
In this work, we study the interface obtained by depositing a monolayer of a Blatter radical
derivative on polycrystalline cobalt. By examining the occupied and unoccupied states at the …

Triggered integer charge transfer: energy-level alignment at an organic-2D material interface

M Schaal, A Baby, M Gruenewald, F Otto… - Nanoscale …, 2024 - pubs.rsc.org
Weakly interacting systems such as organic molecules on monolayers of hexagonal boron
nitride (h-BN) offer the possibility of single integer charge transfer leading to the formation of …