Multiscale and multistep ordering of flow-induced nucleation of polymers

K Cui, Z Ma, N Tian, F Su, D Liu, L Li - Chemical reviews, 2018 - ACS Publications
Flow-induced crystallization (FIC) is a typical nonequilibrium phase transition and a core
industry subject for the largest group of commercially useful polymeric materials …

State of the‐art for extrudate swell of molten polymers: from fundamental understanding at molecular scale toward optimal die design at final product scale

D Tang, FH Marchesini, L Cardon… - Macromolecular …, 2020 - Wiley Online Library
Polymer extrudate swell is a rheological phenomenon taking place after polymer melt flow
emerges the die exit of extrusion equipment, due to flow redistributions and molecular stress …

Disentanglement effects on welding behaviour of polymer melts during the fused-filament-fabrication method for additive manufacturing

C McIlroy, PD Olmsted - Polymer, 2017 - Elsevier
Although 3D printing has the potential to transform manufacturing processes, the strength of
printed parts often does not rival that of traditionally-manufactured parts. The fused-filament …

Deformation of an amorphous polymer during the fused-filament-fabrication method for additive manufacturing

C McIlroy, PD Olmsted - Journal of Rheology, 2017 - pubs.aip.org
Three-dimensional (3D) printing is rapidly becoming an effective means of prototyping and
creating custom consumer goods. The most common method for printing a polymer melt is …

Heterogeneity in polymer melts from melting of polymer crystals

S Rastogi, DR Lippits, GWM Peters, R Graf, Y Yao… - Nature materials, 2005 - nature.com
Semi-crystalline polymers containing amorphous and crystalline regions usually have
intimately mixed chains. The resulting topological constraints (entanglements) in the …

Stress relaxation, dynamics, and plasticity of transient polymer networks

F Meng, RH Pritchard, EM Terentjev - Macromolecules, 2016 - ACS Publications
We propose a theoretical framework for dealing with a transient polymer network
undergoing small deformations, based on the rate of breaking and reforming of network …

Simple constitutive equation for linear polymer melts derived from molecular theory: Rolie–Poly equation

AE Likhtman, RS Graham - Journal of Non-Newtonian Fluid Mechanics, 2003 - Elsevier
Recently we developed a theory for fast flows of entangled polymer melts which includes the
processes of reptation, convective and reptation-driven constraint release, chain stretch and …

Shear and extensional rheology of polystyrene melts and solutions with the same number of entanglements

S Costanzo, Q Huang, G Ianniruberto… - …, 2016 - ACS Publications
We investigate the nonlinear shear and uniaxial extensional rheology of entangled
polystyrene (PS) melts and solutions having the same number Z of entanglements, hence …

Modelling flow-enhanced crystallisation during fused filament fabrication of semi-crystalline polymer melts

C McIlroy, RS Graham - Additive Manufacturing, 2018 - Elsevier
Achieving better control in fused filament fabrication (FFF) relies on a molecular
understanding of how thermoplastic printing materials behave during the printing process …

Primitive path networks generated by annealing and geometrical methods: Insights into differences

S Shanbhag, M Kröger - Macromolecules, 2007 - ACS Publications
Existing methods to obtain the primitive path network for monodisperse, linear polymers in
the molten state are critically compared. A connection is established between the original …