Organocatalytic domino/cascade reactions provide a convenient method for the construction
of complex molecular structures bearing multiple stereocenters in a highly stereoselective …

Conspectus Asymmetric catalysis has been considered to be the most intriguing means for
building collections of functionalized optically active compounds. In particular, metal and …

Since its advent two decades ago, asymmetric organo/transition-metal combined catalysis
(AOMC), including cooperative catalysis and relay catalysis, has leveraged redistribution of …

This review covers the addition of diazo compounds to ketones to afford homologated
ketones, either in the presence or in the absence of promoters or catalysts. Reactions with …

The release of the inherent ring strain of cyclobutane and cyclopropane derivatives allows a
rapid build-up of molecular complexity. This review highlights the state-of-the-art of the ring …

An Ir (I)/squaramide cooperative catalytic strategy for atroposelective synthesis of axially
chiral aryltriazoles has been developed for the first time. Diverse structurally novel …

Enantioselective construction of all-carbon quaternary stereocenters has attracted much
attention over the past few decades. A variety of catalytic asymmetric methods have been …

A rare example of a one‐pot process that involves asymmetric triple relay catalysis is
reported. The key step is an asymmetric [1, 5] electrocyclic reaction of functionalized …

The merger of two powerful synthetic strategies, ie, asymmetric semipinacol-type
rearrangement and transition-metal-catalyzed propargylic alkylation, has been achieved …

A combination of either ruthenium (II) or rhodium (II) complexes and quinine‐derived
squaramide enables 3‐diazooxindoles, indoles, and nitroalkenes to undergo highly efficient …