Aziridines are the nitrogen analogues of epoxides and exhibit similar reactivity patterns as
electrophilic reagents. 1 They undergo highly regio-and stereoselective transformations and …

Aziridines are saturated three-membered heterocycles containing one nitrogen atom. These
compounds are among the most fascinating intermediates in organic synthesis, acting as …

The synthetic uses of organicdiazo compounds for carbenoid transformations have
undergone a renais-sance in recent years as a result of the development of new transition …

Amidation of a variety of hydrocarbons with PhI NTs catalyzed by ruthenium and manganese
meso-tetrakis (pentafluorophenyl) porphyrins 1 and 2 afforded N-substituted amides in up to …

The introduction of nitrogen atoms into small molecules is of fundamental importance and it
is vital that ever more efficient and selective methods for achieving this are developed. With …

The mechanism of the copper-catalyzed aziridination of alkenes using [N-(p-toluenesulfonyl)
imino] phenyliodinane (PhINTs) as the nitrene source has been elucidated by a combination …

[RuVI (TMP)(NSO2R) 2](SO2R= Ms, Ts, Bs, Cs, Ns; R= p-C6H4OMe, p-C6H4Me, C6H5, p-
C6H4Cl, p-C6H4NO2, respectively) and [RuVI (Por)(NTs) 2](Por= 2, 6-Cl2TPP, F20-TPP) …

Structurally related to iodosylbenzene PhI= O, iodonium imidesPhI= NR, off-white to pale
yellow solids of low solubility, belongto the class of hypervalent iodine (III) reagents and …

The mechanism of cobalt (II) porphyrin-mediated aziridination of styrene with PhSO2N3 was
studied by means of DFT calculations. The computations clearly indicate the involvement of …

The deprotection of the chiral N-sulfonyl aziridines 1− 3 has been studied under different
desulfonylation conditions. Two methods for the efficient deprotection of 2-benzyl-, 2-phenyl …