Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a
powerful tool for forging two C–C bonds in a single reaction. Building upon the powerful …

1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

Conspectus Difluoroalkylated compounds play a remarkably important role in life and
materials sciences because of the unique characteristics of the difluoromethylene (CF2) …

The merger of electrochemistry and transition metal catalysis has emerged as a powerful
tool to join two electrophiles in an enantioselective manner. However, the development of …

Alkene dicarbofunctionalizations enable the streamlined construction of aliphatic structures
and have thus been the subject of intense research efforts. Despite significant progress …

A visible-light-promoted photoredox/nickel protocol for the enantioselective three-
component carboarylation of alkenes with tertiary and secondary alkyltrifluoroborates and …

The direct difunctionalization of alkenes, a cheap and abundant feedstock, represents one of
the most attractive strategies for increasing molecular complexity in synthetic organic …

Transition metal (TM)‐catalyzed difunctionalization of unactivated olefins with two carbon‐
based entities is a powerful method to construct complex molecular architectures rapidly …