Copper catalyzed atom transfer radical cyclization reactions

AJ Clark - European Journal of Organic Chemistry, 2016 - Wiley Online Library
Atom transfer radical cyclization (ATRC) is a powerful technique to prepare functionalized 4–
10 membered ring systems using transition metal catalysts. In this review recent advances in …

Efficient Regio- and Stereoselective Formation of Azocan-2-ones via 8-Endo Cyclization of α-Carbamoyl Radicals

X Fang, K Liu, C Li - Journal of the American Chemical Society, 2010 - ACS Publications
The iodine-atom-transfer 8-endo cyclization of α-carbamoyl radicals was investigated
experimentally and theoretically. With the aid of Mg (ClO4) 2 and a bis (oxazoline) ligand, N …

Synthesis of Chlorinated Bicyclic C-Fused Tetrahydrofuro[3,2-c]azetidin-2-ones

RN Ram, N Kumar, N Singh - The Journal of Organic Chemistry, 2010 - ACS Publications
Some bicyclic C-fused chlorinated tetrahydrofuro [3, 2-c] azetidin-2-ones were prepared by a
fairly general route involving Staudinger reaction of allylic/propargylic imidates with …

Synthesis of a D-ring isomer of galanthamine via a radical-based Smiles rearrangement reaction

P Lan, CJ Jackson, MG Banwell… - The Journal of Organic …, 2014 - ACS Publications
The 1, 9-ethanoiminomethano-bridged tetrahydrodibenzo [b, d]-furan 2, a non-natural
isomer of the alkaloid (−)-galanthamine (1) varying in the manner in which the D-ring is …

Synthesis, Properties, and Two‐Dimensional Adsorption Characteristics of [6] Hexahelicene‐7‐carboxylic acid

MW van der Meijden, T Balandina… - … A European Journal, 2016 - Wiley Online Library
A convergent synthesis of racemic [6] hexahelicene‐7‐carboxylic acid by cross‐coupling of
a bicyclic and a tricyclic component is described. A metal‐catalyzed ring‐closure is also a …

Direct and Stereoselective Synthesis of Diversely Substituted 2,4‐trans‐(NH)‐Pyrrolidines by Copper(I)‐Catalyzed Radical Cyclization at Low Temperature

RN Ram, DK Gupta - Advanced Synthesis & Catalysis, 2016 - Wiley Online Library
This work describes a successful copper (I)‐catalyzed radical cyclization of β‐
haloethylallylamines bearing an unprotected NH‐group while retaining catalyst‐redox …

Synthesis, spectroscopic, and thermal analyses of binuclear mixed ligand Co (II) and Ni (II) complexes

S Singh, D Saini, SK Mehta… - Journal of …, 2011 - Taylor & Francis
Two isostructural mixed ligand binuclear metal complexes,[Co2 (µ2-H2O)(µ2-L1) 2 (L1) 2
(L2) 2] 0.5 C7H8 (1) and [Ni2 (µ2-H2O)(µ2-L1) 2 (L1) 2 (L2) 2] 0.5 C6H6 (2)(L1= CCl3COO …

Changing stereoselectivity and regioselectivity in copper (I)-catalyzed 5-exo cyclization by chelation and rigidity in aminoalkyl radicals: Synthesis towards diverse …

S Sadanandan, DK Gupta - New Journal of Chemistry, 2020 - pubs.rsc.org
The work reveals that a chelate-type interaction in the transition state of a β-aminoalkyl
radical in a copper (I)-catalyzed 5-exo-trig radical cyclization step changes the usual …

Polycyclic Aromatic Hydrocarbons and their Adducts with Solvents from Ag (II) SO4-Based Oxidative CC Coupling

PJ Leszczyński, T Jaroń, PJ Malinowski… - Polycyclic Aromatic …, 2019 - Taylor & Francis
bianthryl and 9, 9′-biphenanthryl were synthesized by direct oxidative C–C coupling of
anthracene and phenanthrene, respectively, using divalent silver sulfate Ag (II) SO 4 under …

Atom transfer radical cyclization of O-allyl-2, 2-dichlorohemiacetal acetates: an expedient method to dichloro-γ-lactones

F Ghelfi, F Roncaglia, M Pattarozzi, V Giangiordano… - Tetrahedron, 2009 - Elsevier
3-Alkyl-3-chloro-4-chloromethyl-γ-lactones were synthesized in acceptable yields, exploiting
the CuCl-N, N, N′, N ″, N ″-pentamethyldiethylenetriamine catalyzed atom transfer …