Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Hydride transfer reactions catalyzed by cobalt complexes
W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …
characteristics and outstanding catalytic performance in addition to being cheap and earth …
Iron catalysis in organic synthesis
I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …
June 2014 and represents a comprehensive update of a previous article published by Bolm …
Isomerization of allylbenzenes
The “phenylpropenoids” are a well-known set of naturally occurring compounds obtained
mainly from plant sources. 1, 2 Of this group, the generalized 2-propenylbenzenes 1 and 1 …
mainly from plant sources. 1, 2 Of this group, the generalized 2-propenylbenzenes 1 and 1 …
Controllable isomerization of alkenes by dual visible‐light‐cobalt catalysis
QY Meng, TE Schirmer, K Katou… - Angewandte Chemie …, 2019 - Wiley Online Library
We report herein that thermodynamic and kinetic isomerization of alkenes can be
accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the …
accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the …
Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2
A Gonzalez-de-Castro, J Xiao - Journal of the American Chemical …, 2015 - ACS Publications
A mild and operationally simple iron-catalyzed protocol for the selective aerobic oxidation of
aromatic olefins to carbonyl compounds is described. Catalyzed by a Fe (III) species bearing …
aromatic olefins to carbonyl compounds is described. Catalyzed by a Fe (III) species bearing …
Iron-catalyzed enantioselective cross-coupling reactions of α-chloroesters with aryl Grignard reagents
M Jin, L Adak, M Nakamura - Journal of the American Chemical …, 2015 - ACS Publications
The first iron-catalyzed enantioselective cross-coupling reaction between an organometallic
compound and an organic electrophile is reported. Synthetically versatile racemic α-chloro …
compound and an organic electrophile is reported. Synthetically versatile racemic α-chloro …
Synthesis of Aryl C-Glycosides via Iron-Catalyzed Cross Coupling of Halosugars: Stereoselective Anomeric Arylation of Glycosyl Radicals
L Adak, S Kawamura, G Toma… - Journal of the …, 2017 - ACS Publications
We have developed a novel diastereoselective iron-catalyzed cross-coupling reaction of
various glycosyl halides with aryl metal reagents for the efficient synthesis of aryl C …
various glycosyl halides with aryl metal reagents for the efficient synthesis of aryl C …
Iron-catalyzed tunable and site-selective olefin transposition
The catalytic isomerization of C–C double bonds is an indispensable chemical
transformation used to deliver higher-value analogues and has important utility in the …
transformation used to deliver higher-value analogues and has important utility in the …
Isomerization–hydroformylation tandem reactions
M Vilches-Herrera, L Domke, A Börner - ACS Catalysis, 2014 - ACS Publications
The metal-catalyzed isomerization–hydroformylation tandem reaction is of great importance
for the production of linear aldehydes starting from internal olefins, but also, the shift of the …
for the production of linear aldehydes starting from internal olefins, but also, the shift of the …