Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Hydride transfer reactions catalyzed by cobalt complexes

W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Isomerization of allylbenzenes

M Hassam, A Taher, GE Arnott, IR Green… - Chemical …, 2015 - ACS Publications
The “phenylpropenoids” are a well-known set of naturally occurring compounds obtained
mainly from plant sources. 1, 2 Of this group, the generalized 2-propenylbenzenes 1 and 1 …

Controllable isomerization of alkenes by dual visible‐light‐cobalt catalysis

QY Meng, TE Schirmer, K Katou… - Angewandte Chemie …, 2019 - Wiley Online Library
We report herein that thermodynamic and kinetic isomerization of alkenes can be
accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the …

Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2

A Gonzalez-de-Castro, J Xiao - Journal of the American Chemical …, 2015 - ACS Publications
A mild and operationally simple iron-catalyzed protocol for the selective aerobic oxidation of
aromatic olefins to carbonyl compounds is described. Catalyzed by a Fe (III) species bearing …

Iron-catalyzed enantioselective cross-coupling reactions of α-chloroesters with aryl Grignard reagents

M Jin, L Adak, M Nakamura - Journal of the American Chemical …, 2015 - ACS Publications
The first iron-catalyzed enantioselective cross-coupling reaction between an organometallic
compound and an organic electrophile is reported. Synthetically versatile racemic α-chloro …

Synthesis of Aryl C-Glycosides via Iron-Catalyzed Cross Coupling of Halosugars: Stereoselective Anomeric Arylation of Glycosyl Radicals

L Adak, S Kawamura, G Toma… - Journal of the …, 2017 - ACS Publications
We have developed a novel diastereoselective iron-catalyzed cross-coupling reaction of
various glycosyl halides with aryl metal reagents for the efficient synthesis of aryl C …

Iron-catalyzed tunable and site-selective olefin transposition

X Yu, H Zhao, P Li, MJ Koh - Journal of the American Chemical …, 2020 - ACS Publications
The catalytic isomerization of C–C double bonds is an indispensable chemical
transformation used to deliver higher-value analogues and has important utility in the …

Isomerization–hydroformylation tandem reactions

M Vilches-Herrera, L Domke, A Börner - ACS Catalysis, 2014 - ACS Publications
The metal-catalyzed isomerization–hydroformylation tandem reaction is of great importance
for the production of linear aldehydes starting from internal olefins, but also, the shift of the …