[HTML][HTML] Photofunctionality of iron (III) N-heterocyclic carbenes and related d5 transition metal complexes

P Chábera, L Lindh, NW Rosemann, O Prakash… - Coordination Chemistry …, 2021 - Elsevier
Despite a few reports of photoluminescent and strongly photo-oxidizing transition metal
complexes with ad 5 electronic configuration, the photophysics and photochemistry of this …

Photoactive complexes with earth-abundant metals

OS Wenger - Journal of the American Chemical Society, 2018 - ACS Publications
In this invited Perspective, recent developments and possible future directions of research
on photoactive coordination compounds made from nonprecious transition metal elements …

Photophysics and photochemistry of iron carbene complexes for solar energy conversion and photocatalysis

L Lindh, P Chábera, NW Rosemann, J Uhlig… - Catalysts, 2020 - mdpi.com
Earth-abundant first row transition metal complexes are important for the development of
large-scale photocatalytic and solar energy conversion applications. Coordination …

Is iron the new ruthenium?

OS Wenger - Chemistry–A European Journal, 2019 - Wiley Online Library
Ruthenium complexes with polypyridine ligands are very popular choices for applications in
photophysics and photochemistry, for example, in lighting, sensing, solar cells, and …

Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes

T Ogawa, N Sinha, B Pfund, A Prescimone… - Journal of the …, 2022 - ACS Publications
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …

Intraligand excited states turn a ruthenium oligothiophene complex into a light-triggered Ubertoxin with anticancer effects in extreme hypoxia

JA Roque III, HD Cole, PC Barrett… - Journal of the …, 2022 - ACS Publications
Ru (II) complexes that undergo photosubstitution reactions from triplet metal-centered (3MC)
excited states are of interest in photochemotherapy (PCT) due to their potential to produce …

[HTML][HTML] Iron(ii) coordination complexes with panchromatic absorption and nanosecond charge-transfer excited state lifetimes

JD Braun, IB Lozada, C Kolodziej, C Burda… - Nature …, 2019 - nature.com
Replacing current benchmark rare-element photosensitizers with ones based on abundant
and low-cost metals such as iron would help facilitate the large-scale implementation of …

Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived 2LMCT Excited States

O Prakash, L Lindh, N Kaul, NW Rosemann… - Inorganic …, 2022 - ACS Publications
Fe (III) complexes with N-heterocyclic carbene (NHC) ligands belong to the rare examples of
Earth-abundant transition metal complexes with long-lived luminescent charge-transfer …

Ru (II) Phenanthroline-Based Oligothienyl Complexes as Phototherapy Agents

HD Cole, A Vali, JA Roque III, G Shi, G Kaur… - Inorganic …, 2023 - ACS Publications
Ru (II) polypyridyl complexes have gained widespread attention as photosensitizers for
photodynamic therapy (PDT). Herein, we systematically investigate a series of the type [Ru …

Multifaceted Deactivation Dynamics of Fe(II) N-Heterocyclic Carbene Photosensitizers

L Lindh, T Pascher, S Persson, Y Goriya… - The Journal of …, 2023 - ACS Publications
Excited state dynamics of three iron (II) carbene complexes that serve as prototype Earth-
abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant …