[HTML][HTML] A post-functionalization toolbox for diazonium (electro)-grafted surfaces: Review of the coupling methods

C Gautier, I López, T Breton - Materials Advances, 2021 - pubs.rsc.org
The surface modification by organics has been booming over the past twenty years in the
context of the development of 2D nanomaterials for a wide range of applications. The …

[HTML][HTML] Os (ii/iii) complex supports pH-insensitive electrochemical DNA-based sensing with superior operational stability than the benchmark methylene blue reporter

MA Pellitero, N Kundu, J Sczepanski, N Arroyo-Currás - Analyst, 2023 - pubs.rsc.org
DNA-based electrochemical sensors use redox reporters to transduce affinity events into
electrical currents. Ideally, such reporters must be electrochemically reversible, chemically …

Systematic design of electrochromic energy storage devices based on metal–organic monolayers

NO Laschuk, II Ebralidze, EB Easton… - ACS Applied Energy …, 2021 - ACS Publications
Electrochromic materials (ECMs) change their colored state with changes in potential. When
applied as an energy storage device, they reveal the current state of charge using intrinsic …

Covalent grafting of dielectric films on Cu (111) surface via electrochemical reduction of aryl diazonium salts

L Cao, Y Wu, T Hang, M Li - Langmuir, 2022 - ACS Publications
Covalent grafting of dielectric films containing polyhedral oligomeric silsesquioxane (POSS)
on the surface of Cu (111) is performed by a one-step electrochemical reduction of …

Covalently anchored carboxyphenyl monolayer via aryldiazonium ion grafting: A well-defined reactive tether layer for on-surface chemistry

L Lee, H Ma, PA Brooksby, SA Brown, YR Leroux… - Langmuir, 2014 - ACS Publications
Electrografting of aryl films to electrode surfaces from diazonium ion solutions is a widely
used method for preparation of modified electrodes. In the absence of deliberate measures …

Molecular and electronic structure of electroactive self-assembled monolayers

LP Mendez De Leo, E de la Llave, D Scherlis… - The Journal of …, 2013 - pubs.aip.org
Self-assembled monolayers (SAMs) containing electroactive functional groups are excellent
model systems for the formation of electronic devices by self-assembly. In particular …

Attachment of organic layers to materials surfaces by reduction of diazonium salts

J Pinson - Aryl diazonium salts: New coupling agents in …, 2012 - Wiley Online Library
Aromatic diazonium salts (ArN 2+ X−) are easily synthesized in an acidic aqueous medium
(HBF 4) starting from an amine in the presence of NaNO 2, and in an aprotic medium (ACN+ …

Some evidence for the formation of an azo bond during the electroreduction of diazonium salts on Au substrates

AM Ricci, LP Méndez De Leo, FJ Williams… - …, 2012 - Wiley Online Library
Molecular films obtained by electrochemical reduction of diazoniuim tetrafluoroborate salts
[4‐carboxybenzene (PhCOOH) and 4‐amino‐(2, 3, 5, 6‐tetrafluoro)‐carboxybenzene …

[HTML][HTML] Mechanistic Insights into Anion-Induced Electrochromism of Ru (II)-Based Metallo-Supramolecular Polymer

X Fu, Z Zhang, Z Cao, AA Rogachev, MA Yarmolenko… - Polymers, 2023 - mdpi.com
The metallo-supramolecular polymer (MSP) is considered one of the most promising
electrodes for electrochromic devices due to its intrinsically stable redox properties …

Interaction of 4-imidazolemethanol with a copper electrode revealed by isotope-edited SERS and theoretical modeling

I Matulaitienė, E Pociūtė, Z Kuodis… - Physical Chemistry …, 2015 - pubs.rsc.org
Adsorption of 4-imidazolemethanol (ImMeOH) on a copper electrode has been investigated
by in situ isotope-edited (H/D and 63Cu/65Cu) surface enhanced Raman spectroscopy …