The previous systems of triple‐bond and single‐bond self‐consistent, additive covalent radii,
R (AB)= r (A)+ r (B), are completed with a fit for σ2π2 double‐bonds. The primary bond …

This review aims to look at the development of Raman spectroscopy as applied to the field of
cement science. Starting with a historical overview, it then considers the spectra of cements …

Our first review article in 2006 outlined the observation, photochemical properties, and
theoretical investigations of a new breed of small transition-metal complexes with CM …

The manuscript reports the synthesis, characterization, and analysis of electronic structure in
a series of complexes of small perfluorocarbon ligands with the (PNP) Rh fragment (where …

The new fluorocarbynes [M (CF)(CO) 2 (Tp*)](M= Mo, W; Tp*= tris (dimethylpyrazolyl) borate)
arise from electrophilic fluorination of the lithiocarbynes [M (CLi)(CO) 2 (Tp*)] with FN …

Reactions of laser-ablated Pt atoms with CH4 and C2H6 produce CH3− PtH and CH3CH2−
PtH via oxidative C− H insertion and show that the Pt atom is an effective C− H insertion …

A novel method for kp measurement is presented, in which time‐resolved electron
paramagnetic resonance detection of radical concentration after applying a single laser …

Laser-ablated lanthanide metal atoms were condensed with CH2F2 in excess argon at 6 K
or neon at 4 K. New infrared absorption bands are assigned to the oxidative addition product …

Reaction of CHI3 with six equivalents of CrCl2 in THF at low temperatures affords [Cr3Cl3
(μ2‐Cl) 3 (μ3‐CH)(thf) 6] as the first isolable high‐yield CrIII μ3‐methylidyne complex …

The successive treatment of [W (CO) 6] with LiSiPh3,(OCBr) 2, and 4-picoline (pic) affords
the silylcarbyne complex [W ( CSiPh3) Br (CO) 2 (pic) 2], which reacts with 1, 2-bis …