Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Ultrahard magnetism from mixed-valence dilanthanide complexes with metal-metal bonding

CA Gould, KR McClain, D Reta, JGC Kragskow… - Science, 2022 - science.org
Metal-metal bonding interactions can engender outstanding magnetic properties in bulk
materials and molecules, and examples abound for the transition metals. Extending this …

Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K

Z Zhu, C Zhao, T Feng, X Liu, X Ying, XL Li… - Journal of the …, 2021 - ACS Publications
Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

FS Guo, BM Day, YC Chen, ML Tong, A Mansikkamäki… - Science, 2018 - science.org
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

CAP Goodwin, F Ortu, D Reta, NF Chilton, DP Mills - Nature, 2017 - nature.com
Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands

JC Vanjak, BO Wilkins, V Vieru… - Journal of the …, 2022 - ACS Publications
The first example of a homoleptic f-block borolide sandwich complex is presented and
shown to be a high-performance single-molecule magnet (SMM). The bis (borolide) complex …

High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets

KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …