Organic reactions in aqueous media with a focus on carbon− carbon bond formations: a decade update

CJ Li - Chemical Reviews, 2005 - ACS Publications
Organic syntheses are composed of two main types of reactions: Carbon-carbon bond
formations and functional group transformations. CC bond formation is the essence of …

Do secondary orbital interactions really exist?

JI García, JA Mayoral, L Salvatella - Accounts of chemical …, 2000 - ACS Publications
A revision of the most typical examples used to illustrate the existence of secondary orbital
interactions (SOI) has been achieved. However, our analysis indicates that no conclusive …

[图书][B] Molecular orbitals and organic chemical reactions

I Fleming - 2011 - books.google.com
Winner of the PROSE Award for Chemistry & Physics 2010 Acknowledging the very best in
professional and scholarly publishing, the annual PROSE Awards recognise publishers' and …

[图书][B] Comprehensive organic reactions in aqueous media

CJ Li, TH Chan - 2007 - books.google.com
An extensive update of the classic reference on organic reactions in water Published almost
a decade ago, the first edition has served as the guide for research in this burgeoning field …

Diels_Alder reactions in water

S Otto, JBFN Engberts - Pure and applied chemistry, 2000 - degruyter.com
This review illustrates how water, as an environmentally friendly solvent, can have
significant additional benefits when it is used as a solvent for the Diels_Alder reaction. The …

Water as solvent in organic synthesis

A Lubineau, J Augé - Modern solvents in organic synthesis, 1999 - Springer
Organic reactions using water as solvent are reviewed with a focus on pericyclic reactions,
carbonyl additions, stoichiometric organometallic reactions, oxidations and reductions which …

A rationalization of the solvent effect on the Diels–Alder reaction in ionic liquids using multiparameter linear solvation energy relationships

R Bini, C Chiappe, VL Mestre, CS Pomelli… - Organic & biomolecular …, 2008 - pubs.rsc.org
The Diels–Alder reaction between cyclopentadiene and three dienophiles (acrolein, methyl
acrylate and acrylonitrile) having different hydrogen bond acceptor abilities has been carried …

The solvent effect on the Diels–Alder reaction in ionic liquids: multiparameter linear solvation energy relationships and theoretical analysis

C Chiappe, M Malvaldi, CS Pomelli - Green chemistry, 2010 - pubs.rsc.org
This review illustrates how ionic liquid properties can affect Diels–Alder reactions. The
mechanisms by which ionic solvents enhance the rate and selectivity of the reaction are …

Density Functional Theory Study of Aqueous-Phase Rate Acceleration and Endo/Exo Selectivity of the Butadiene and Acrolein Diels−Alder Reaction

S Kong, JD Evanseck - Journal of the American Chemical Society, 2000 - ACS Publications
The four stereospecific transition structures of the butadiene and acrolein Diels− Alder
reaction have been studied using the Becke three-parameter density functional theory with …

Rationalisation of Solvent Effects in the Diels Alder Reaction Between Cyclopentadiene and Methyl Acrylate in Room Temperature Ionic Liquids

A Vidiš, CA Ohlin, G Laurenczy… - Advanced Synthesis …, 2005 - Wiley Online Library
Abstract The Diels–Alder reaction between cyclopentadiene and methyl acrylate in ionic
liquids has been studied in detail. The effect of contamination of the ionic liquids by common …