This review is focused on the analysis of current data on new methods of alkenylation of
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …

Free radicals are important subjects in organic, bioorganic, medicinal, material, and
atmospheric chemistries. Synthetic utilities of free radicals have been well-accomplished in …

An unprecedented radical difluoromethylarylation reaction of alkynes has been developed
by discovering a new difluoromethylation reagent, CF2HSO2NHNHBoc. This air-stable and …

Ag2CO3-catalyzed difunctionalization of alkynes via a radical phosphonation and C–H
functionalization tandem process was developed to synthesize various 3-phosphonated …

The vernal blooming of green chemistry has contributed to the development of visible light
catalysis. Active radical species are generated from catalytic amounts of photosensitizers …

An effective photoredox-mediated tandem phosphorylation/cyclization reaction of
diphenylphosphine oxide with three types of radical acceptors leads to P (O) Ph2-containing …

Silver-catalyzed cascade difunctionalization of N-(p-methoxyaryl) propiolamides coupled
with dearomatization was achieved and used to regiospecifically construct a variety of …

The development of P (O)–heteroatom bond-forming reactions is of vital importance.
However, previous methods all have their own limitations and drawbacks. Herein, we …

Organophosphorus compounds have all along attracted considerable attention as they have
broad utilities such as reagents for chemical reactions, ligands for transition metal catalysts …

Previously, we developed a gold-catalyzed cycloisomerization of dienediynes to synthesize
the fused 6, 7, 5-tricyclic compounds. This reaction involves aliphatic C–H functionalization …