Concerted reactions that produce diradicals and zwitterions: electronic, steric, conformational, and kinetic control of cycloaromatization processes

RK Mohamed, PW Peterson, IV Alabugin - Chemical Reviews, 2013 - ACS Publications
The broad utility of cyclic structures accounts for the key roles that cycle-forming reactions
play in synthetic designs. Most of these reactions can be classified as either a cyclization of …

[HTML][HTML] Fluorescence modulation by amines: Mechanistic insights into twisted intramolecular charge transfer (TICT) and beyond

C Chen, C Fang - Chemosensors, 2023 - mdpi.com
Amine groups are common constituents of organic dyes and play important roles in tuning
fluorescence properties. In particular, intensive research works have demonstrated the …

The role of hydrogen bonding in excited state intramolecular charge transfer

FAS Chipem, A Mishra… - Physical Chemistry …, 2012 - pubs.rsc.org
Intramolecular charge transfer (ICT) that occurs upon photoexcitation of molecules is a vital
process in nature and it has ample applications in chemistry and biology. The ICT process of …

Time-resolved fluorescence study of aggregation-induced emission enhancement by restriction of intramolecular charge transfer state

BR Gao, HY Wang, YW Hao, LM Fu… - The Journal of …, 2010 - ACS Publications
Cyano-substituted oligo (α-phenylenevinylene)-1, 4-bis (R-cyano-4-diphenylaminostyryl)-2,
5-diphenylbenzene (CNDPASDB) molecules are studied in solution and aggregate state by …

Photoinduced Intramolecular Charge Transfer and S2 Fluorescence in Thiophene‐π‐Conjugated Donor–Acceptor Systems: Experimental and TDDFT Studies

GJ Zhao, RK Chen, MT Sun, JY Liu… - … A European Journal, 2008 - Wiley Online Library
Experimental and theoretical methods were used to study newly synthesized thiophene‐π‐
conjugated donor–acceptor compounds, which were found to exhibit efficient intramolecular …

Toward designed singlet fission: solution photophysics of two indirectly coupled covalent dimers of 1, 3-diphenylisobenzofuran

JC Johnson, A Akdag, M Zamadar… - The Journal of …, 2013 - ACS Publications
In order to identify optimal conditions for singlet fission, we are examining the photophysics
of 1, 3-diphenylisobenzofuran (1) dimers covalently coupled in various ways. In the two …

Fast intramolecular charge transfer with a planar rigidized electron donor/acceptor molecule

T Yoshihara, SI Druzhinin… - Journal of the American …, 2004 - ACS Publications
The planar rigidized molecule fluorazene (FPP) undergoes fast reversible intramolecular
charge transfer (ICT) in the excited state, with a reaction time of 12 ps in the polar solvent …

Metal chelation-controlled twisted intramolecular charge transfer and its application to fluorescent sensing of metal ions and anions

S Aoki, D Kagata, M Shiro, K Takeda… - Journal of the American …, 2004 - ACS Publications
Two fluorescent ligands, N-(2-(5-cyanopyridyl)) cyclen (L5) and N-(2-pyridyl) cyclen
(L6)(cyclen= 1, 4, 7, 10-tetraazacyclododecane), were designed and synthesized to control …

Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes

JS Yang, KL Liau, CM Wang… - Journal of the American …, 2004 - ACS Publications
The photochemical behavior of trans-4-(N-arylamino) stilbene (1, aryl= 4-substituted phenyl)
in solvents more polar than THF is strongly dependent on the substituent in the N-aryl group …

Intramolecular Charge Transfer with the Planarized 4-Aminobenzonitrile 1-tert-Butyl-6-cyano-1,2,3,4-tetrahydroquinoline (NTC6)

KA Zachariasse, SI Druzhinin, W Bosch… - Journal of the …, 2004 - ACS Publications
Fast and efficient intramolecular charge transfer (ICT) and dual fluorescence is observed
with the planarized aminobenzonitrile 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline …