Concerted reactions that produce diradicals and zwitterions: electronic, steric, conformational, and kinetic control of cycloaromatization processes
RK Mohamed, PW Peterson, IV Alabugin - Chemical Reviews, 2013 - ACS Publications
The broad utility of cyclic structures accounts for the key roles that cycle-forming reactions
play in synthetic designs. Most of these reactions can be classified as either a cyclization of …
play in synthetic designs. Most of these reactions can be classified as either a cyclization of …
[HTML][HTML] Fluorescence modulation by amines: Mechanistic insights into twisted intramolecular charge transfer (TICT) and beyond
Amine groups are common constituents of organic dyes and play important roles in tuning
fluorescence properties. In particular, intensive research works have demonstrated the …
fluorescence properties. In particular, intensive research works have demonstrated the …
The role of hydrogen bonding in excited state intramolecular charge transfer
FAS Chipem, A Mishra… - Physical Chemistry …, 2012 - pubs.rsc.org
Intramolecular charge transfer (ICT) that occurs upon photoexcitation of molecules is a vital
process in nature and it has ample applications in chemistry and biology. The ICT process of …
process in nature and it has ample applications in chemistry and biology. The ICT process of …
Time-resolved fluorescence study of aggregation-induced emission enhancement by restriction of intramolecular charge transfer state
BR Gao, HY Wang, YW Hao, LM Fu… - The Journal of …, 2010 - ACS Publications
Cyano-substituted oligo (α-phenylenevinylene)-1, 4-bis (R-cyano-4-diphenylaminostyryl)-2,
5-diphenylbenzene (CNDPASDB) molecules are studied in solution and aggregate state by …
5-diphenylbenzene (CNDPASDB) molecules are studied in solution and aggregate state by …
Photoinduced Intramolecular Charge Transfer and S2 Fluorescence in Thiophene‐π‐Conjugated Donor–Acceptor Systems: Experimental and TDDFT Studies
GJ Zhao, RK Chen, MT Sun, JY Liu… - … A European Journal, 2008 - Wiley Online Library
Experimental and theoretical methods were used to study newly synthesized thiophene‐π‐
conjugated donor–acceptor compounds, which were found to exhibit efficient intramolecular …
conjugated donor–acceptor compounds, which were found to exhibit efficient intramolecular …
Toward designed singlet fission: solution photophysics of two indirectly coupled covalent dimers of 1, 3-diphenylisobenzofuran
In order to identify optimal conditions for singlet fission, we are examining the photophysics
of 1, 3-diphenylisobenzofuran (1) dimers covalently coupled in various ways. In the two …
of 1, 3-diphenylisobenzofuran (1) dimers covalently coupled in various ways. In the two …
Fast intramolecular charge transfer with a planar rigidized electron donor/acceptor molecule
T Yoshihara, SI Druzhinin… - Journal of the American …, 2004 - ACS Publications
The planar rigidized molecule fluorazene (FPP) undergoes fast reversible intramolecular
charge transfer (ICT) in the excited state, with a reaction time of 12 ps in the polar solvent …
charge transfer (ICT) in the excited state, with a reaction time of 12 ps in the polar solvent …
Metal chelation-controlled twisted intramolecular charge transfer and its application to fluorescent sensing of metal ions and anions
S Aoki, D Kagata, M Shiro, K Takeda… - Journal of the American …, 2004 - ACS Publications
Two fluorescent ligands, N-(2-(5-cyanopyridyl)) cyclen (L5) and N-(2-pyridyl) cyclen
(L6)(cyclen= 1, 4, 7, 10-tetraazacyclododecane), were designed and synthesized to control …
(L6)(cyclen= 1, 4, 7, 10-tetraazacyclododecane), were designed and synthesized to control …
Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes
JS Yang, KL Liau, CM Wang… - Journal of the American …, 2004 - ACS Publications
The photochemical behavior of trans-4-(N-arylamino) stilbene (1, aryl= 4-substituted phenyl)
in solvents more polar than THF is strongly dependent on the substituent in the N-aryl group …
in solvents more polar than THF is strongly dependent on the substituent in the N-aryl group …
Intramolecular Charge Transfer with the Planarized 4-Aminobenzonitrile 1-tert-Butyl-6-cyano-1,2,3,4-tetrahydroquinoline (NTC6)
KA Zachariasse, SI Druzhinin, W Bosch… - Journal of the …, 2004 - ACS Publications
Fast and efficient intramolecular charge transfer (ICT) and dual fluorescence is observed
with the planarized aminobenzonitrile 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline …
with the planarized aminobenzonitrile 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline …