Modeling of magnesium-decorated graphene quantum dot nanostructure for trapping AsH 3, PH 3 and NH 3 gases
A magnesium-decorated graphene quantum dot (C24H12-Mg) surface has been examined
theoretically using density functional theory (DFT) computations at the ωB97XD/6-311++ G …
theoretically using density functional theory (DFT) computations at the ωB97XD/6-311++ G …
Sterically Hindered Tellurium (IV) Catecholate as a Lewis Acid
PA Petrov, EA Filippova, TS Sukhikh… - Inorganic …, 2022 - ACS Publications
Sterically hindered tellurium catecholate Te (Cat36) 2 (Cat36= 3, 6-di-tert-butyl-catecholate)
was synthesized with the reaction of amorphous Te with 3, 6-di-tert-butyl-o-benzoquinone …
was synthesized with the reaction of amorphous Te with 3, 6-di-tert-butyl-o-benzoquinone …
Capturing an Eigen complex in an acid-base reaction shows step-resolved molecularity
Summary In the Eigen-Weller framework, acid-base reactions are described as those
consisting of serial steps. The steps include the encounter of acid and base compounds …
consisting of serial steps. The steps include the encounter of acid and base compounds …
Adducts of a sterically hindered tellurium (iv) catecholate with diimines
PA Petrov, EA Filippova, TS Sukhikh… - New Journal of …, 2024 - pubs.rsc.org
Adducts of sterically hindered tellurium catecholate Te (Cat36) 2 (Cat36= 3, 6-di-tert-butyl-
catecholate) with diimine ligands were isolated and characterized by means of single crystal …
catecholate) with diimine ligands were isolated and characterized by means of single crystal …
Chemical Evolution in Solutions of Ir Complex [H(dmso)2]2[IrCl6]. Structures of [H(dmso)2]2[IrCl6], [H(dmso)][IrCl4(dmso)2], [Me2SCH2C(O)Me][IrCl4(dmso)2], [Me2SCH2C(O) …
OV Rudnitskaya, TA Tereshina… - European Journal of …, 2022 - Wiley Online Library
An iridium complex [H (dmso) 2] 2 [IrCl6](1) is synthesized via the reaction of H2IrCl6 with
DMSO in an acetone solution. The substance is thoroughly characterized using UV‐Vis …
DMSO in an acetone solution. The substance is thoroughly characterized using UV‐Vis …
First Iridium(IV) Chloride–Dimethyl Sulfoxide Complex [H(dmso)2][IrCl5(dmso-κO)]: Synthesis and Structure along with Novel Polymorph Modifications of [H(dmso)2][trans-IrCl4(dmso-κS)2] and [H …
As evidenced by UV–Vis and EPR spectroscopies, the reaction of H2IrCl6· 6H2O or Na2
[IrCl6]· n H2O with DMSO results in a slow reduction of Ir (IV) avoiding the formation of Ir (IV) …
[IrCl6]· n H2O with DMSO results in a slow reduction of Ir (IV) avoiding the formation of Ir (IV) …