Natural tracer profiles across argillaceous formations

M Mazurek, P Alt-Epping, A Bath, T Gimmi… - Applied …, 2011 - Elsevier
Argillaceous formations generally act as aquitards because of their low hydraulic
conductivities. This property, together with the large retention capacity of clays for cationic …

Reactive transport modeling of coupled processes in nanoporous media

C Tournassat, CI Steefel - Reviews in Mineralogy and …, 2019 - pubs.geoscienceworld.org
Nanoporous media consist of homogeneous or heterogeneous porous material in which a
significant part of the pore size distribution lies in the nanometer range. Clayey rocks …

Multicomponent diffusion of a suite of tracers (HTO, Cl, Br, I, Na, Sr, Cs) in a single sample of Opalinus Clay

CAJ Appelo, LR Van Loon, P Wersin - Geochimica et Cosmochimica Acta, 2010 - Elsevier
Diffusion experiments with HTO, 36Cl−, Br−, I−, 22Na+, 85Sr2+ and 134Cs+ at trace
concentrations in a single sample of Opalinus Clay are modeled with PHREEQC's …

Coupled thermo-hydro-mechanical processes in the near field of a high-level radioactive waste repository in clay formations

CF Tsang, JD Barnichon, J Birkholzer, XL Li… - International Journal of …, 2012 - Elsevier
The present paper provides an overview of key coupled thermo-hydro-mechanical (THM)
processes in clay formations that would result from the development of a high-level …

[HTML][HTML] Relevance of diffuse-layer, Stern-layer and interlayers for diffusion in clays: a new model and its application to Na, Sr, and Cs data in bentonite

P Krejci, T Gimmi, LR Van Loon, M Glaus - Applied Clay Science, 2023 - Elsevier
The diffusive flux of cations is enhanced and that of anions is decreased compared to that of
water tracers in bentonite or other clays, as a result of electrostatic interactions between ions …

[HTML][HTML] Modeling of heat and solute transport in a fracture-matrix mine thermal energy storage system and energy storage performance evaluation

C Chen, M Binder, L Oppelt, Y Hu, C Engelmann… - Journal of …, 2024 - Elsevier
Repurposing groundwater-filled mine cavities for thermal energy storage has demonstrated
promising potential to buffer the imbalance of energy supply and demand. Fractured …

Sorption of uranium (VI) onto Opalinus Clay in the absence and presence of humic acid in Opalinus Clay pore water

C Joseph, K Schmeide, S Sachs, V Brendler, G Geipel… - Chemical …, 2011 - Elsevier
The U (VI) sorption onto Opalinus Clay (OPA), a natural clay rock from Mont Terri,
Switzerland, was investigated in the absence and presence of humic acid under aerobic …

How mobile are sorbed cations in clays and clay rocks?

T Gimmi, G Kosakowski - Environmental science & technology, 2011 - ACS Publications
Diffusion of cations and other contaminants through clays is of central interest, because
clays and clay rocks are widely considered as barrier materials for waste disposal sites. An …

Ionic transport in nano-porous clays with consideration of electrostatic effects

C Tournassat, CI Steefel - Reviews in Mineralogy and …, 2015 - pubs.geoscienceworld.org
The mineralogical and chemical properties of clays have been the subject of longstanding
study in the research community—in fact, entire journals are devoted to the topic. In the field …

Simulating Donnan equilibria based on the Nernst-Planck equation

T Gimmi, P Alt-Epping - Geochimica et Cosmochimica Acta, 2018 - Elsevier
Understanding ion transport through clays and clay membranes is important for many
geochemical and environmental applications. Ion transport is affected by electrostatic forces …