Recent advances in the synthesis and applications of macrocyclic arenes

XN Han, Y Han, CF Chen - Chemical Society Reviews, 2023 - pubs.rsc.org
Macrocyclic arenes including calixarenes, resorcinarenes, cyclotriveratrylene, pillararenes
and so on have emerged as highly attractive synthetic macrocyclic hosts due to their unique …

Surveying macrocyclic chemistry: from flexible crown ethers to rigid cyclophanes

Z Liu, SKM Nalluri, JF Stoddart - Chemical Society Reviews, 2017 - pubs.rsc.org
Macrocycles are molecular entities that display a combination of molecular recognition and
complexation properties with vital implications for host–guest/supramolecular chemistry …

Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry

T Ogoshi, T Yamagishi, Y Nakamoto - Chemical reviews, 2016 - ACS Publications
In 2008, we reported a new class of pillar-shaped macrocyclic hosts, known as “pillar [n]
arenes”. Today, pillar [n] arenes are recognized as key players in supramolecular chemistry …

Functionalizing Pillar[n]arenes

NL Strutt, H Zhang, ST Schneebeli… - Accounts of chemical …, 2014 - ACS Publications
Conspectus Macrocyclic chemistry has relied on the dominance of some key cavitands,
including cyclodextrins, calixarenes, cyclophanes, and cucurbiturils, to advance the field of …

Saucer[n]arenes: Synthesis, Structure, Complexation, and Guest‐Induced Circularly Polarized Luminescence Property

J Li, HY Zhou, Y Han, CF Chen - … Chemie International Edition, 2021 - Wiley Online Library
Macrocycles denoted as saucer [n] arenes (n= 4, 5) were easily synthesized by the one‐pot
condensation of 2, 7‐dimethoxynaphthalene (2, 7‐DMN) and paraformaldehyde in the …

Macrocyclic host molecules with aromatic building blocks: the state of the art and progress

Q Shi, X Wang, B Liu, P Qiao, J Li… - Chemical Communications, 2021 - pubs.rsc.org
Macrocyclic host molecules play the central role in host–guest chemistry and
supramolecular chemistry. The highly structural symmetry of macrocyclic host molecules can …

New opportunities in synthetic macrocyclic arenes

JR Wu, YW Yang - Chemical Communications, 2019 - pubs.rsc.org
Synthetic macrocyclic receptors generally display unique geometries, preorganized cavities,
and tunable binding affinities, which facilitate their application in numerous fields including …

Tiara [5] arenes: Synthesis, Solid‐State Conformational Studies, Host–Guest Properties, and Application as Nonporous Adaptive Crystals

W Yang, K Samanta, X Wan… - Angewandte Chemie …, 2020 - Wiley Online Library
Abstract Tiara [5] arenes (T [5] s), a new class of five‐fold symmetric oligophenolic
macrocycles that are not accessible from the addition of formaldehyde to phenol, were …

Design, synthesis and applications of responsive macrocycles

J Yu, D Qi, J Li - Communications Chemistry, 2020 - nature.com
Inspired by the lock and key principle, the development of supramolecular macrocyclic
chemistry has promoted the prosperous growth of host-guest chemistry. The updated …

Biphen [n] arenes

H Chen, J Fan, X Hu, J Ma, S Wang, J Li, Y Yu… - Chemical …, 2015 - pubs.rsc.org
To design and exploit novel macrocyclic synthetic receptors is a permanent and challenging
topic in supramolecular chemistry. Here we describe the one-pot synthesis, unique …