Chemistry of coordination space of porous coordination polymers

S Kitagawa, R Matsuda - Coordination Chemistry Reviews, 2007 - Elsevier
Recently, syntheses of epoch-making space materials using coordination compounds are
underway by various groups. The rational synthetic strategy of the space of coordination …

Unraveling structure and dynamics in porous frameworks via advanced in situ characterization techniques

V Bon, E Brunner, A Pöppl… - Advanced Functional …, 2020 - Wiley Online Library
Dynamic metal–organic frameworks (MOFs) represent a subgroup of frameworks featuring
unique performance, as they are capable of adapting their pore size and/or the orientation of …

[HTML][HTML] X-ray analysis on the nanogram to microgram scale using porous complexes

Y Inokuma, S Yoshioka, J Ariyoshi, T Arai, Y Hitora… - Nature, 2013 - nature.com
X-ray single-crystal diffraction (SCD) analysis has the intrinsic limitation that the target
molecules must be obtained as single crystals. Here we report a protocol for SCD analysis …

Designable assembly of aluminum molecular rings for sequential confinement of iodine molecules

CH Liu, WH Fang, Y Sun, S Yao… - Angewandte Chemie …, 2021 - Wiley Online Library
Although numerous adsorbent materials have been reported for the capture of radioactive
iodine, there is still demand for new absorbents that are economically viable and can be …

Microporous metal− organic frameworks incorporating 1, 4-benzeneditetrazolate: Syntheses, structures, and hydrogen storage properties

M Dinca, AF Yu, JR Long - Journal of the American Chemical …, 2006 - ACS Publications
The potential of tetrazolate-based ligands for forming metal− organic frameworks of utility in
hydrogen storage is demonstrated with the use of 1, 4-benzeneditetrazolate (BDT2-) to …

Flexibility in metal-organic framework materials: Impact on sorption properties

AJ Fletcher, KM Thomas, MJ Rosseinsky - Journal of Solid State Chemistry, 2005 - Elsevier
Recent years have seen the development of a new class of porous coordination polymers
known collectively as metal organic framework materials (MOFs). This review outlines recent …

Temperature-or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer

JP Zhang, YY Lin, WX Zhang… - Journal of the American …, 2005 - ACS Publications
Aside from a temperature-induced structural transformation, a new nanoporous coordination
polymer [Ag6Cl (atz) 4]⊙ OH⊙ 6H2O (Hatz= 3-amino-1, 2, 4,-triazole) comprised of …

Supramolecular isomerism, framework flexibility, unsaturated metal center, and porous property of Ag (I)/Cu (I) 3, 3 ', 5, 5 '-tetrametyl-4, 4 '-bipyrazolate

JP Zhang, S Kitagawa - Journal of the American Chemical Society, 2008 - ACS Publications
Template-controlled reactions of 3, 3 ', 5, 5 '-tetramethyl-4, 4 '-bipyrazole (H2bpz) with [Ag
(NH3) 2]+ or [Cu (NH3) 2]+ give binary metal bipyrazolates [M2 (bpz)](M= Ag, Cu) as two …

Structural changes and coordinatively unsaturated metal atoms on dehydration of honeycomb analogous microporous metal–organic frameworks

PDC Dietzel, RE Johnsen, R Blom… - Chemistry–A European …, 2008 - Wiley Online Library
Porous metal–organic framework compounds with coordinatively unsaturated metal sites on
the inner surface of the pores promise to be valuable adsorbents and catalyst systems …

Crystal engineering of coordination polymers using 4, 4′-bipyridine as a bond between transition metal atoms

K Biradha, M Sarkar, L Rajput - Chemical communications, 2006 - pubs.rsc.org
Coordination polymers have attracted an enormous interest among chemists due to their
novel physical and chemical properties. This review describes the role of 4, 4′-bipyridine in …