The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds

SE Gilson, PC Burns - Coordination Chemistry Reviews, 2021 - Elsevier
Structures of 388 neptunium-bearing crystal structures are sorted into an expanded
structural hierarchy and examined. The majority of structures contain Np (V)(149), Np …

Developing the 134Ce and 134La pair as companion positron emission tomography diagnostic isotopes for 225Ac and 227Th radiotherapeutics

TA Bailey, V Mocko, KM Shield, DD An, AC Akin… - Nature Chemistry, 2021 - nature.com
Developing targeted α-therapies has the potential to transform how diseases are treated. In
these interventions, targeting vectors are labelled with α-emitting radioisotopes that deliver …

Multiple bonding in lanthanides and actinides: Direct comparison of covalency in thorium (IV)-and cerium (IV)-imido complexes

T Cheisson, KD Kersey, N Mahieu… - Journal of the …, 2019 - ACS Publications
A series of thorium (IV)-imido complexes was synthesized and characterized. Extensive
experimental and computational comparisons with the isostructural cerium (IV)-imido …

A series of dithiocarbamates for americium, curium, and californium

SK Cary, J Su, SS Galley, TE Albrecht-Schmitt… - Dalton …, 2018 - pubs.rsc.org
Characterizing how actinide properties change across the f-element series is critical for
improving predictive capabilities and solving many nuclear problems facing our society …

Proton-Coupled Electron Transfer at the Pu5+/4+ Couple

KS Otte, JE Niklas, CM Studvick… - Journal of the …, 2024 - ACS Publications
The synthesis and solution and solid-state characterization of [Pu4+ (NPC) 4], 1-
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …

The coordination chemistry of Cm III, Am III, and Ac III in nitrate solutions: an actinide L 3-edge EXAFS study

MG Ferrier, BW Stein, SE Bone, SK Cary, AS Ditter… - Chemical …, 2018 - pubs.rsc.org
Understanding actinide (III)(AnIII= CmIII, AmIII, AcIII) solution-phase speciation is critical for
controlling many actinide processing schemes, ranging from medical applications to …

Ultra-selective ligand-driven separation of strategic actinides

GJP Deblonde, A Ricano, RJ Abergel - Nature communications, 2019 - nature.com
Metal ion separations are critical to numerous fields, including nuclear medicine, waste
recycling, space exploration, and fundamental research. Nonetheless, operational …

Experimental and theoretical insight into the ionic liquid-mediated complexation of trivalent lanthanides with β-diketone and its fluorinated analogue

A Nagar, A Srivastava, A Sengupta, MA Sk… - Inorganic …, 2024 - ACS Publications
A multitechnique approach with theoretical insights has been employed to understand the
complexation of trivalent lanthanides with two β-diketones, viz. 1-phenyl-1, 3-butanedione (L …

Series of tetravalent actinide amidinates: structure determination and bonding analysis

R Kloditz, S Fichter, S Kaufmann, TS Brunner… - Inorganic …, 2020 - ACS Publications
Two series of isostructural tetravalent actinide amidinates [AnX ((S)-PEBA) 3](An= Th, U, Np;
X= Cl, N3) bearing the chiral (S, S)-N, N′-bis (1-phenylethyl) benzamidinate ((S)-PEBA) …

Systematic comparison of the structure of homoleptic tetradentate N 2 O 2-type Schiff base complexes of tetravalent f-elements (M (iv)= Ce, Th, U, Np, and Pu) in solid …

T Radoske, R Kloditz, S Fichter, J März, P Kaden… - Dalton …, 2020 - pubs.rsc.org
A series of tetradentate N2O2-type Schiff base complexes with tetravalent 4f-and 5f-block
metals,[M (salpn) 2](H2salpn= N, N′-disalicylidene-1, 3-diaminopropane; M= Ce, Th, U …