Due to the heterometallic synergistic effects from different metals, heterometallic clusters are
of great importance in small-molecule activation and catalysis. For example, both biological …

Conspectus Heterometallic clusters with M–M bonds have significantly interested chemists
because of their attractive structures and synergistic effects in small-molecule activation and …

A unique thorium‐thorium bond was observed in the crystalline tri‐thorium cluster [{Th (η8‐
C8H8)(μ3‐Cl) 2} 3 {K (THF) 2} 2]∞, though the claim of σ‐aromaticity for Th3 bond has been …

A synergistic anion photoelectron spectroscopic and ab initio computational study of
photodetachment of UF–is reported. The measurement determined a vertical detachment …

Modeling actinides with electronic structure theories is challenging because these systems
present a strong ligand field and metal–ligand covalency. We systematically investigate the …

The modeling of spin–orbit coupling (SOC) remains a challenge in computational chemistry
due to the high computational cost. With the rising popularity of spin-driven processes and f …

The metal-metal bonds involved in f-block elements have attracted hefty interest during
recent years because of their fascinating structures and unique properties. Auxiliary ligands …

This work for the first time addresses the feasibility of measuring millihertz gravitational
waves (mHz GWs) with a storage ring-based detector. While this overall challenge consists …

The actinide–actinide bonding in tri‐actinide clusters [An₃Cl₆] ᶻ (An= Ac–Pu, z= 1–6) and
[An₃Cl₆Cp₃] ᶻ (z=− 2–+ 3; Cp=(η5‐C5H5)) is studied using density functional theory. We …

We report the structural, vibrational, and optical properties of americium formate (Am (CHO2)
3) crystals synthesized via the in situ hydrolysis of dimethylformamide (DMF). The …