Ionisable amino‐lipid is a key component in lipid nanoparticles (LNPs), which plays a crucial
role in the encapsulation of RNA molecules, allowing efficient cellular uptake and then …

Charge plays a crucial role in the function of molecular and supramolecular systems, but
coordination hosts capable of orthogonal charge regulation remain elusive so far. In this …

Biological encapsulants, such as viral capsids and ferritin protein cages, use many identical
subunits to tile the surface of a polyhedron. Inspired by these natural systems, synthetic …

This work introduces the use of 8-aminoquinoline subcomponents to generate complex
three-dimensional structures. Together with a tris (formylpyridine), 8-aminoquinoline …

An enantiopure ligand with four bidentate metal-binding sites and four (S)-carbon
stereocenters self-assembles with octahedral ZnII or CoII to produce O-symmetric M8L6 …

Chemical reactions inside the confined pockets of enzyme-mimicking hosts, such as cages
and macrocycles, have been an emerging field of interest over the past decade. Although …

Spin-crossover (SCO) coordination cages are at the forefront of research for their potential in
crafting next-generation molecular devices. However, due to the scarcity of SCO hosts and …

Precise control over guest release and recapture using external stimuli is a valuable goal,
potentially enabling new modes of chemical purification. Including redox moieties within the …

The use of copper (I) in metal–organic assemblies leads readily to the formation of simple
grids and helicates, whereas higher-order structures require complex ligand designs. Here …

A tetrahedral FeII4L4 cage assembled from the coordination of triangular chiral, face-
capping ligands to iron (II). This cage exists as two diastereomers in solution, which differ in …