Binding mechanisms in supramolecular complexes

HJ Schneider - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Forces to reckon with: Supramolecular complexes, such as the one shown, are normally
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …

Molecular ratchets and kinetic asymmetry: Giving chemistry direction

S Borsley, DA Leigh… - Angewandte Chemie …, 2024 - Wiley Online Library
Over the last two decades ratchet mechanisms have transformed the understanding and
design of stochastic molecular systems—biological, chemical and physical—in a move away …

Dissecting solvent effects on hydrogen bonding

NY Meredith, S Borsley, IV Smolyar… - Angewandte Chemie …, 2022 - Wiley Online Library
The experimental isolation of H‐bond energetics from the typically dominant influence of the
solvent remains challenging. Here we use synthetic molecular balances to quantify …

Perylene Bisimide Dimer Aggregates: Fundamental Insights into Self‐Assembly by NMR and UV/Vis Spectroscopy

C Shao, M Grüne, M Stolte… - Chemistry–A European …, 2012 - Wiley Online Library
A novel perylene bisimide (PBI) dye bearing one solubilizing dialkoxybenzyl and one bulky
2, 5‐di‐tert‐butylphenyl substituent was synthesized and its aggregation behavior was …

Alternative motifs for halogen bonding

RW Troff, T Mäkelä, F Topić, A Valkonen… - European Journal of …, 2013 - Wiley Online Library
The halogen‐bonding interaction is one of the rising stars in supramolecular chemistry.
Although other weak interactions and their influence on the structure and chemistry of …

Bindungsmechanismen in supramolekularen Komplexen

HJ Schneider - Angewandte Chemie, 2009 - Wiley Online Library
Abstract Kräfte‐Sammelsurium: Supramolekulare Komplexe, wie der gezeigte, beruhen
meist auf einer Kombination unterschiedlichster Wechselwirkungen, wie Ionenpaarbildung …

Stepwise Functionalization of a Pillar [5] arene‐Containing [2] Rotaxane with Pentafluorophenyl Ester Stoppers

N Becharguia, E Wasielewski, R Abidi… - … A European Journal, 2024 - Wiley Online Library
Detailed investigations into the stepwise bis‐functionalization of a pillar [5] arene‐containing
rotaxane building block have been carried out. Upon a first stopper exchange, the pillar [5] …

Accelerated Post‐Polymerization Amidation of Polymers with Side‐Chain Ester Groups by Intramolecular Activation

JFR Van Guyse, MN Leiske, J Verjans… - Angewandte …, 2022 - Wiley Online Library
The catalytic conversion of esters to amides represents new opportunities in the synthetic
diversification and upcycling of polymers, as esters are commonly featured in various …

Quantifying Intermolecular Interactions in Asymmetric Peptide Organocatalysis as a Key toward Understanding Selectivity

J Nowag, M Brauser, L Steuernagel… - Journal of the …, 2023 - ACS Publications
The kinetic resolution of trans-cyclohexane-1, 2-diol with a lipophilic oligopeptide catalyst
shows extraordinary selectivities. To improve our understanding of the factors governing …

Solvent geometry regulated cooperative supramolecular polymerization

H Kar, G Ghosh, S Ghosh - Chemistry–A European Journal, 2017 - Wiley Online Library
This article discloses hydrogen‐bonding driven supramolecular polymerization of a core‐
substituted naphthalene‐diimide derivative NDI‐1, which exhibits J‐aggregation in all tested …