This review focuses on the synthesis, reactivity and structural chemistry of zinc hydroxides
and oxides derived essentially from organozinc compounds. It demonstrates the advantages …

The chemical transformation of lactic acid derivatives to industrially important fine chemicals
is crucial for the development of new techniques in the medical, cosmetics, and food sectors …

Six directed hydrogen bonding (H-bonding) interactions allow for the reversible capture and
reduction of dioxygen to a trans-1, 2-peroxo within a tripodal zinc (II) framework …

This paper reports a series of comparative experiments on the activity of carbon-and oxygen-
centred radical species in a model reaction of the radical addition of THF to imines mediated …

The hydrolysis reaction between Brønsted basic organometallic or metal–amide reagents
with Brønsted acidic OH groups from water or metal–hydroxides may act as a controlled …

Reactions of diethylzinc with TEMPO were investigated. Dropwise addition of 1 equiv of
TEMPO to Et2Zn at− 10° C leads to the nitroxide complex EtZn (TEMPO) in high yield …

Ethylzinc derivatives of ortho‐hydroxybiphenyl and 2, 6‐diphenylphenol that bear different
nuclearity and dispositions of aromatic rings toward the metal center were synthesized and …

Reactions between O2 and organometallics with non‐redox‐active metal centers have
received continuous interest for over 150 years, although significant uncertainties …

In this paper a series of Mg (II), Li (I) and Zn (II) complexes based on two families of amine
bis (phenolate) s have been prepared and structurally characterised. In the solid-state the Li …

Despite decades of extensive studies on the reactivity of magnesium alkyls towards O2, the
isolation and structural characterization of discrete products of these reactions still remains a …