The same oxygenation-state introduction of hypervalent sulfur under transition-metal-free conditions

D Zeng, M Wang, WP Deng, X Jiang - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Sulfonyl compounds have attracted considerable interest due to their extensive applications
in drug discovery. Access to the assembly of SO2-containing compounds via the …

Synthesis and applications of thiosulfonates and selenosulfonates as free-radical reagents

X Wang, J Meng, D Zhao, S Tang, K Sun - Chinese Chemical Letters, 2023 - Elsevier
Chalcogenative sulfones (thiosulfonates and selenosulfonates), as reactants for organic
transformations, are widely used and interesting because of their potential to react with …

Non-isocyanate Polythiourethane Network from Biowaste: Achieving Circularity via Multidimensional Chemical Recycling with Valuable Small-Molecule Recovery and …

Y Chen, N Mielke, NS Purwanto, B Chen… - …, 2023 - ACS Publications
We studied and established the dual nature of non-isocyanate polythiourethane (NIPTU)
dynamic chemistry and capitalized on our understanding to achieve multidimensional …

Electrochemical sulfonylation of thiols with sulfonyl hydrazides: a metal-and oxidant-free protocol for the synthesis of thiosulfonates

ZY Mo, TR Swaroop, W Tong, YZ Zhang, HT Tang… - Green …, 2018 - pubs.rsc.org
An efficient electrochemical transformation of structurally diverse sulfonyl hydrazides and
thiols into thiosulfonates in the presence of ammonium iodide as redox catalyst and …

Transition Metal‐Free Synthesis of Carbamates Using CO2 as the Carbon Source

W Schilling, S Das - ChemSusChem, 2020 - Wiley Online Library
Utilization of carbon dioxide as a C1 synthon is highly attractive for the synthesis of valuable
chemicals. However, activation of CO2 is highly challenging, owing to its thermodynamic …

Thiosulfonylation of unactivated alkenes with visible-light organic photocatalysis

K Gadde, P Mampuys, A Guidetti, HYV Ching… - Acs …, 2020 - ACS Publications
A metal-free method for the vicinal thiosulfonylation of unactivated alkenes with
thiosulfonates using 9-mesityl-10-methylacridinium perchlorate as the photo-organocatalyst …

Thiosulfonates as emerging reactants: synthesis and applications

P Mampuys, CR McElroy, JH Clark… - Advanced Synthesis …, 2020 - Wiley Online Library
The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed
from their original discovery to recent advances. Incorporation of the green credentials of the …

Visible-light-enabled construction of thiocarbamates from isocyanides, thiols, and water at room temperature

W Wei, P Bao, H Yue, S Liu, L Wang, Y Li… - Organic letters, 2018 - ACS Publications
A convenient visible-light-induced method for the synthesis of thiocarbamates from
isocyanides, thiols, and water has been developed under mild reaction conditions. The …

S-alkyl Dithiocarbamates Synthesis through Electrochemical Multicomponent Reaction of Thiols, Hydrogen Sulfide, and Isocyanides

X Liu, T Cai, M Zhu, Y Liu, J Xia, J Xie… - The Journal of …, 2023 - ACS Publications
Dithiocarbamates synthesis is extremely important in plenty of biomedical and agrochemical
applications, especially fungicide development, but remains a great challenge. In this work …

Disproportionate Coupling Reaction of Sodium Sulfinates Mediated by BF3·OEt2: An Approach to Symmetrical/Unsymmetrical Thiosulfonates

L Cao, SH Luo, K Jiang, ZF Hao, BW Wang… - Organic …, 2018 - ACS Publications
The BF3· OEt2-mediated disproportionate coupling reaction of sodium sulfinates was found
for the first time. In this reaction, various S–S (O) 2 bonds can be formed, efficiently giving …