Ion soft landing: A unique tool for understanding electrochemical processes

V Prabhakaran, GE Johnson, J Laskin - Current Opinion in Electrochemistry, 2023 - Elsevier
Ion soft landing (SL) is a preparative mass spectrometry approach that enables deposition of
mass-and charge-selected gaseous ions onto surfaces with controlled kinetic energy. The …

Controlled Formation of Fused Metal Chalcogenide Nanoclusters Using Soft Landing of Gaseous Fragment Ions

H Gholipour-Ranjbar, HY Samayoa-Oviedo, J Laskin - ACS nano, 2023 - ACS Publications
The complete ligation of nanoclusters significantly reduces their chemical reactivity, catalytic
activity, and charge transfer properties. Therefore, in applications, nanoclusters are activated …

Gas-phase ion chemistry of [B12X12] 2−(X= F, Cl, Br, I, CN) A brief review of twelve years of researching twelve− vertexed dianions and their fragments

J Warneke - International Journal of Mass Spectrometry, 2023 - Elsevier
The closo-dodecaborate dianions [B 12 X 12] 2−(X= halogen, CN) have been recognized in
recent years for their outstanding physical and chemical properties. Gas-phase ion …

Chemical Synthesis with Gaseous Molecular Ions: Harvesting [B12Br11N2] from a Mass Spectrometer

M Rohdenburg, Z Warneke, H Knorke… - Angewandte Chemie …, 2023 - Wiley Online Library
Mass spectrometry frequently reveals the existence of transient gas phase ions that have not
been synthesized in solution or in bulk. These elusive ions are, therefore, often considered …

Design and performance of a soft-landing instrument for fragment ion deposition

HY Samayoa-Oviedo, KA Behrend, S Kawa… - Analytical …, 2021 - ACS Publications
We report the development of a new high-flux electrospray ionization-based instrument for
soft landing of mass-selected fragment ions onto surfaces. Collision-induced dissociation is …

Multiplexing of electrospray ionization sources using orthogonal injection into an electrodynamic ion funnel

P Su, X Chen, AJ Smith, MF Espenship… - Analytical …, 2021 - ACS Publications
In this contribution, we report an efficient approach to multiplex electrospray ionization (ESI)
sources for applications in analytical and preparative mass spectrometry. This is achieved …

A preparative mass spectrometer to deposit intact large native protein complexes

P Fremdling, TK Esser, B Saha, AA Makarov, KL Fort… - ACS …, 2022 - ACS Publications
Electrospray ion-beam deposition (ES-IBD) is a versatile tool to study the structure and
reactivity of molecules from small metal clusters to large protein assemblies. It brings …

On-surface single-molecule identification of mass-selected cyclodextrin-supported polyoxovanadates for multistate resistive-switching memory applications

F Yang, M Moors, DA Hoang, S Schmitz… - ACS Applied Nano …, 2022 - ACS Publications
Polyoxovanadate anions immobilized on conducting substrates are promising candidates
for molecule-based memory technologies. However, strong electronic interactions with the …

Formation and characterization of polymetallic {CrxMy} rings in vacuo

N Geue, GA Timco, GFS Whitehead, EJL McInnes… - Nature …, 2023 - nature.com
Understanding the (dis) assembly mechanisms of large metallosupramolecules is critical in
their design, stability and application. The inherent complexity of these structures leads to …

Anion–Anion Chemistry with Mass‐Selected Molecular Fragments on Surfaces

F Yang, KA Behrend, H Knorke… - Angewandte Chemie …, 2021 - Wiley Online Library
While reactions between ions and neutral molecules in the gas phase have been studied
extensively, reactions between molecular ions of same polarity remain relatively unexplored …