Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Selenium environmental cycling and bioavailability: a structural chemist point of view

A Fernández-Martínez, L Charlet - Reviews in Environmental Science and …, 2009 - Springer
Selenium is usually known as the 'double-edged sword element'for its dual toxic and
beneficial character to health. Since the pioneer works by Schwarz and Foltz on the …

Selenite reduction by mackinawite, magnetite and siderite: XAS characterization of nanosized redox products

AC Scheinost, L Charlet - Environmental science & technology, 2008 - ACS Publications
Suboxic soils and sediments often contain the Fe (II)-bearing minerals mackinawite (FeS),
siderite (FeCO3) or magnetite (Fe3O4), which should be able to reduce aqueous selenite …

Sediment phosphorus speciation and mobility under dynamic redox conditions

CT Parsons, F Rezanezhad, DW O'Connell… - …, 2017 - bg.copernicus.org
Anthropogenic nutrient enrichment has caused phosphorus (P) accumulation in many
freshwater sediments, raising concerns that internal loading from legacy P may delay the …

A robust model for pore-water chemistry of clayrock

EC Gaucher, C Tournassat, FJ Pearson, P Blanc… - … et Cosmochimica Acta, 2009 - Elsevier
The chemistry of pore water is an important property of clayrocks being considered as host
rocks for long-term storage of radioactive waste. It may be difficult, if not impossible, to obtain …

Interactions of oxytetracycline with a smectite clay: a spectroscopic study with molecular simulations

L Aristilde, C Marichal, J Miehe-Brendle… - … science & technology, 2010 - ACS Publications
Binding of antibiotics to clay minerals can decrease both their physical and biological
availability in soils. To elucidate the binding mechanisms of tetracycline antibiotics on …

Spectroscopic evidence for Fe (II)–Fe (III) electron transfer at clay mineral edge and basal sites

A Neumann, TL Olson, MM Scherer - Environmental science & …, 2013 - ACS Publications
Despite the importance of Fe redox cycling in clay minerals, the mechanism and location of
electron transfer remain unclear. More specifically, there is some controversy whether …

[HTML][HTML] Freshwater suspended particulate matter—Key components and processes in floc formation and dynamics

H Walch, F von der Kammer, T Hofmann - Water research, 2022 - Elsevier
Freshwater suspended particulate matter (SPM) plays an important role in many
biogeochemical cycles and serves multiple ecosystem functions. Most SPM is present as …

Electron transfer at the mineral/water interface: Selenium reduction by ferrous iron sorbed on clay

L Charlet, AC Scheinost, C Tournassat… - … et Cosmochimica Acta, 2007 - Elsevier
The mobility and availability of the toxic metalloid selenium in the environment are largely
controlled by sorption and redox reactions, which may proceed at temporal scales similar to …

Facile Metal Release from Pore-Lining Phases Enables Unique Carbonate Zonation in a Basalt Carbon Mineralization Demonstration

N Lahiri, QRS Miller, R Cao, CT Depp… - … Science & Technology, 2023 - ACS Publications
Carbon-negative strategies such as geologic carbon sequestration in continental flood
basalts offers a promising route to the removal of greenhouse gases, such as CO2, via safe …