π-Electronic ion pairs: building blocks for supramolecular nanoarchitectonics via i π–i π interactions

Y Haketa, K Yamasumi, H Maeda - Chemical Society Reviews, 2023 - pubs.rsc.org
The pairing of charged π-electronic systems and their ordered arrangement have been
achieved by iπ–iπ interactions that are derived from synergetically worked electrostatic and …

Intense Circularly Polarized Luminescence Induced by Chiral Supramolecular Assembly: The Importance of Intermolecular Electronic Coupling

ZF Liu, XX Liu, H Zhang, L Zeng, LY Niu… - Angewandte …, 2024 - Wiley Online Library
Herein we report on circularly polarized luminescence (CPL) emission originating from
supramolecular chirality of organic microcrystals with a| glum| value up to 0.11. The …

Condensed π-molecular arrangement for–C 2 H 4 SO 3− armed naphthalenediimide

R Ide, A Kawasaki, T Takeda, S Dekura… - Journal of Materials …, 2024 - pubs.rsc.org
A highly condensed packing structure with π-molecules is important to achieve high carrier
transport properties. To realize condensed π-molecular arrangements, we focused on …

Introducing of an Unexplored Aza-BODIPY Diradicaloids with 4-(2,6-Ditert-butyl)phenoxyl Radicals Located in 1,7-Positions of the Aza-BODIPY Core

M Oyelowo, JW Schaffner, TI Jeaydi, DA Blank… - Inorganic …, 2024 - ACS Publications
We have prepared and characterized two diradicaloid systems 5a and 5b that originated
from the oxidation of a 1, 7-(4-(2, 6-di-tert-butyl) phenol)-substituted aza-BODIPY core. The …

Simultaneous discovery of chiral and achiral dyes: elucidating the optical functions of helical and flag-hinged boron tetradentate complexes

L Cui, R Furuta, T Harada, T Konta, Y Hoshino… - Dalton …, 2024 - pubs.rsc.org
The construction of novel complexes can lead to the manifestation of unexpected structures
and properties, thereby making chemical exploration in experiments a potential source for …

N, O-Boron spirocyclic complexes: How Electronic and Spatial Factors Modulate Photophysical and Physicochemical Properties

MV Motverov, KI Lugovik, GV Vataru, AS Minin… - Dyes and …, 2024 - Elsevier
This study presents the synthesis of new spirocyclic boron-coordinated (SBCs) fluorophores
based on a simple and facile procedure and their optical properties. The structure of the …

Borylated β-Fluorinated Pyrroles

M Yokoyama, H Maeda - Chemistry Letters, 2023 - academic.oup.com
Borylated β-fluorinated pyrroles, which are molecules with the potential to be converted into
π-extended derivatives, were synthesized using IrI-catalyzed reactions and their solid-state …

荷電π 電子系の規則配列による機能創出

羽毛田洋平, 前田大光 - 高分子, 2024 - jstage.jst.go.jp
これは, 異なる構成ユニットを交互に精密配置するという点で, 交互共重合体からなるポリマーの
設計と共通している. 一方, 同種電荷種が積層した構造からなる集合体 (電荷種分離配置型集合体) …