The hierarchical aggregation of molecular nanostructures from multiple components is a
grand synthetic challenge, which requires highly selective linkage control. We demonstrate …

Giant heterometallic polyoxometalate (POM) clusters with precise atom structures, flexibly
adjustable and abundant active sites are promising for constructing functional nanodrugs …

Abstract A protein‐sized (ca. 4.2× 4.2× 3.6 nm3) non‐biologically derived molecule
{Nb288O768 (OH) 48 (CO3) 12}(Nb288) containing up to 288 niobium atoms has been …

A series of polyoxometalates (POMs) that incorporate the highest‐nuclearity Ln clusters that
have been observed in such structures to date (Ln26, Ln= La and Ce) are described, which …

The assembly of gigantic heterometallic metal clusters remains a great challenge for
synthetic chemistry. Herein, based on the slow release strategy of lanthanide ions and in situ …

A giant tetrahedral heterometallic polyoxometalate (POM)[Dy30Co8Ge12W108O408 (OH)
42 (OH2) 30] 56−, which shows single‐molecule magnet (SMM) behavior, is described. This …

The development of visible‐light‐induced photocatalysts for chemoselective functional
group transformations has received considerable attention. Polyoxometalates (POMs) are …

A series containing the highest nuclearity polyoxoniobate (PONb) nanoclusters, ranging
from dimers to tetramers, has been obtained. They include one 114‐nuclear {Li8⊂ …

Assembly of small clusters into rigid bodies with precise shape and symmetry has been
witnessed by the significant advances in cluster‐based metal–organic frameworks (MOFs) …

Presented herein are the AlIII molecular ring architectures from 8‐ring to 16‐ring. Although
there are numerous reported cyclic coordination compounds based on transition metals …