Polymer nanocomposite dielectrics: understanding the matrix/particle interface

S Wang, Z Luo, J Liang, J Hu, N Jiang, J He, Q Li - ACS nano, 2022 - ACS Publications
Polymer nanocomposite dielectrics possess exceptional electric properties that are absent
in the pristine dielectric polymers. The matrix/particle interface in polymer nanocomposite …

Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Interphase in polymer nanocomposites

J Huang, J Zhou, M Liu - JACS Au, 2022 - ACS Publications
The lightweight and high-strength functional nanocomposites are important in many
practical applications. Natural biomaterials with excellent mechanical properties provide …

Glass transition of polymers in bulk, confined geometries, and near interfaces

S Napolitano, E Glynos, NB Tito - Reports on Progress in Physics, 2017 - iopscience.iop.org
When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular
mobility. If the process is performed at a constant rate, the structural relaxation time of the …

Unraveling bilayer interfacial features and their effects in polar polymer nanocomposites

X Li, S He, Y Jiang, J Wang, Y Yu, X Liu, F Zhu… - Nature …, 2023 - nature.com
Polymer nanocomposites with nanoparticles dispersed in polymer matrices have attracted
extensive attention due to their significantly improved overall performance, in which the …

Crystallization in thin films of polymer glasses: The role of free surfaces, solid interfaces and their competition

Y Yang, H Tian, S Napolitano, B Zuo - Progress in Polymer Science, 2023 - Elsevier
Polymer coatings of nanometric thickness are about to enter in everyday life as part of a
wide range of applications such as protective layers, stimuli-responsive membranes or as …

Effect of local chain conformation in adsorbed nanolayers on confined polymer molecular mobility

B Zuo, H Zhou, MJB Davis, X Wang, RD Priestley - Physical review letters, 2019 - APS
Interfaces play an important role in modifying the dynamics of polymers confined to the
nanoscale. We demonstrate that the distance over which an interface suppresses molecular …

Unexpected molecular weight effect in polymer nanocomposites

S Cheng, AP Holt, H Wang, F Fan, V Bocharova… - Physical review …, 2016 - APS
The properties of the interfacial layer between the polymer matrix and nanoparticles largely
determine the macroscopic properties of polymer nanocomposites (PNCs). Although the …

Relaxation behavior of polymer thin films: Effects of free surface, buried interface, and geometrical confinement

B Li, S Zhang, JS Andre, Z Chen - Progress in Polymer Science, 2021 - Elsevier
The glass transition temperature (T g) of polymer thin films, one of the most important
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …

Irreversible adsorption of polymer melts and nanoconfinement effects

S Napolitano - Soft Matter, 2020 - pubs.rsc.org
For almost a decade, growing experimental evidence has revealed a strong correlation
between the properties of nanoconfined polymers and the number of chains irreversibly …