Air-Stable Coordinatively Unsaturated Ruthenium (II) Complex for Ligand Binding and Catalytic Transfer Hydrogenation of Ketones from Ethanol

A Beaufils, P Melle, N Lentz, M Albrecht - Inorganic chemistry, 2024 - ACS Publications
Coordinatively unsaturated complexes are interesting from a fundamental level for their
formally empty coordination site and, in particular, from a catalytic perspective as they …

Extraction of 5-Hydroxymethylfurfural and Furfural in Aqueous Biphasic Systems: A COSMO-RS Guided Approach to Greener Solvent Selection

D Soukup-Carne, P López-Porfiri… - ACS Sustainable …, 2024 - ACS Publications
5-Hydroxymethylfurfural (HMF) and furfural (Fur) are promising biobased platform
chemicals, derived from the dehydration of carbohydrate feedstocks, normally conducted in …

Copper-catalyzed C (sp 3)–H alkylation of fluorene with primary and secondary alcohols using a borrowing hydrogen method

R Saha, SK Maharana, NC Jana, B Bagh - Chemical Communications, 2024 - pubs.rsc.org
Despite the limited success of copper-catalyzed alkylations,(NNS) CuCl proved to be an
effective catalyst for the sp3 C–H alkylation of fluorene with alcohols. Various primary …

Cu (II) Coordination Polymers for the Selective Oxidation of Biomass-Derived Veratryl Alcohol in Green Solvents: A Sustainable Catalytic Approach

NC Jana, R Herchel, B Bagh - Inorganic Chemistry, 2024 - ACS Publications
Four air-stable one-dimensional copper (II) coordination polymers (CP1–CP4) with azide
linkers were synthesized using tridentate NNS and NNN ligands. Single-crystal X-ray …

Iron-Catalyzed sp3 C–H Alkylation of Fluorene with Primary and Secondary Alcohols: A Borrowing Hydrogen Approach

R Saha, BC Hembram, S Panda… - The Journal of Organic …, 2024 - ACS Publications
The utilization of earth-abundant, cheap, and nontoxic transition metals in important catalytic
transformations is essential for sustainable development, and iron has gained significant …

Iron-and base-catalyzed C (α)-alkylation and one-pot sequential alkylation–hydroxylation of oxindoles with secondary alcohols

R Saha, BC Hembram, S Panda, NC Jana… - Organic & Biomolecular …, 2024 - pubs.rsc.org
The utilization of economical and environmentally benign transition metals in crucial
catalytic processes is pivotal for sustainable advancement in synthetic organic chemistry …

Piano‐stool dinuclear ruthenium (II) complexes of pyrazine‐carboxylate/carboxamide ligands: Structural studies and catalytic transfer hydrogenation of ketones

RT Kumah, SO Ojwach - Applied Organometallic Chemistry, 2023 - Wiley Online Library
Reactions of ligand pyrazine‐2‐carboxylic acid (HL1) with [Ru (η6‐p‐cymene) Cl2] 2
precursor gave the dinuclear piano‐stool ruthenium (II) complex [{Ru (η6‐p‐cymene) Cl2}‐μ …