Facet‐specific Active Surface Regulation of BixMOy (M=Mo, V, W) Nanosheets for Boosted Photocatalytic CO2 reduction

Y Zhang, X Zhi, JR Harmer, H Xu, K Davey… - Angewandte …, 2022 - Wiley Online Library
Photocatalytic performance can be optimized via introduction of reactive sites. However, it is
practically difficult to engineer these on specific photocatalyst surfaces, because of limited …

C2+ Selectivity for CO2 Electroreduction on Oxidized Cu-Based Catalysts

H Li, Y Jiang, X Li, K Davey, Y Zheng… - Journal of the …, 2023 - ACS Publications
Design for highly selective catalysts for CO2 electroreduction to multicarbon (C2+) fuels is
pressing and important. There is, however, presently a poor understanding of selectivity …

Promoting ethylene production over a wide potential window on Cu crystallites induced and stabilized via current shock and charge delocalization

H Sun, L Chen, L Xiong, K Feng, Y Chen… - Nature …, 2021 - nature.com
Abstract Electrochemical CO2 reduction (CO2RR) in a product-orientated and energy-
efficient manner relies on rational catalyst design guided by mechanistic understandings. In …

Machine Learning Big Data Set Analysis Reveals C–C Electro-Coupling Mechanism

H Li, X Li, P Wang, Z Zhang, K Davey… - Journal of the …, 2024 - ACS Publications
Carbon–carbon (C–C) coupling is essential in the electrocatalytic reduction of CO2 for the
production of green chemicals. However, due to the complexity of the reaction network, there …

C 3 production from CO 2 reduction by concerted* CO trimerization on a single-atom alloy catalyst

L Chen, C Tang, Y Zheng, E Skúlason… - Journal of Materials …, 2022 - pubs.rsc.org
The direct electroreduction of carbon dioxide (CO2) and carbon monoxide (CO) to C3
products is challenging. The main reason is the competitive C2 production resulting from a …

Advancing electrochemical N2 reduction: interfacial electrolyte effects and operando computational approaches

L Jiang, X Bai, X Zhi, K Davey, Y Jiao - EES Catalysis, 2024 - pubs.rsc.org
The electrochemical N2 reduction reaction (eNRR) is a promising pathway for clean and
sustainable production of ammonia, a compound essential for global industry. The …

Controlling C–C coupling reactivity through pore shape engineering of B-doped graphyne family

K Dabsamut, K Takahashi - Carbon, 2024 - Elsevier
Graphyne is an interesting carbon allotrope characterized by sp-sp 2 hybridized carbon
bonds, which allow for structure variability. Though there are studies evaluating the electrical …

New Mechanistic Insights into Electrokinetic Competition Between Nitrogen Reduction and Hydrogen Evolution Reactions

L Jiang, X Bai, X Zhi, Y Jiao - Advanced Energy Materials, 2024 - Wiley Online Library
Achieving both high activity and selectivity presents a significant challenge for
electrochemical N2 reduction (eNRR) due to the competing hydrogen evolution reaction …

Spatial-confinement induced electroreduction of CO and CO 2 to diols on densely-arrayed Cu nanopyramids

L Chen, C Tang, K Davey, Y Zheng, Y Jiao… - Chemical Science, 2021 - pubs.rsc.org
The electroreduction of carbon dioxide (CO2) and carbon monoxide (CO) to liquid alcohol is
of significant research interest. This is because of a high mass-energy density, readiness for …

Accelerating the Reaction Kinetics of CO2 Reduction to Multi‐Carbon Products by Synergistic Effect between Cation and Aprotic Solvent on Copper Electrodes

X Bai, C Chen, X Zhao, Y Zhang… - Angewandte Chemie …, 2024 - Wiley Online Library
Improving the selectivity of electrochemical CO2 reduction to multi‐carbon products (C2+) is
an important and highly challenging topic. In this work, we propose and validate an effective …