Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space
of accessible structures and enabled new synthetic disconnections. The unique properties of …

Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …

REVIEW intricate molecular topologies and architectures. To turn the molecular dreams into
a reality, synthetic chemists must ultimately roll up their sleeves and become molecular …

N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …

Herein, we report a hydrodefluorination reaction of polyfluoroarenes catalyzed by
bismuthinidenes, Phebox-Bi (I) and OMe-Phebox-Bi (I). Mechanistic studies on the …